Recent Advances of CO2 Fixation via Asymmetric Catalysis for the Direct Synthesis of Optically Active Small Molecules

doi:10.6023/cjoc202002032

Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (8): 2208-2220.DOI: 10.6023/cjoc202002032 Previous Articles Next Articles

Special Issue: 二氧化碳虚拟合辑

不对称催化实现的二氧化碳固定直接合成光学活性小分子的最新进展

郭霄^a, 王亚洲^b, 陈洁^b, 李公强^a, 夏纪宝^b

a 南京工业大学先进材料研究院柔性电子重点实验室江苏省国家先进材料协同创新中心南京 211816;
b 中国科学院兰州化学物理研究所中国科学院兰州化学物理研究所苏州研究院羰基合成与选择氧化国家重点实验室分子合成科学卓越创新中心兰州 730000

收稿日期:2020-02-24 修回日期:2020-05-08 发布日期:2020-05-15
通讯作者: 陈洁, 李公强, 夏纪宝 E-mail:chenjie318827@hotmail.com;iamgqli@njtech.edu.cn;jibaoxia@licp.cas.cn
基金资助:
国家自然科学基金（Nos.21702212，21772208）和中国科学院前沿科学基金（No.QYZDJSSW-SLH051）资助项目.

Recent Advances of CO₂ Fixation via Asymmetric Catalysis for the Direct Synthesis of Optically Active Small Molecules

Guo Xiao^a, Wang Yazhou^b, Chen Jie^b, Li Gongqiang^a, Xia Ji-Bao^b

a Key Laboratory of Flexible Electronic&Institute of Advanced Materials, Jiangsu National Synergistic Innovation Center for Advanced Materials, Nanjing Tech University, Nanjing 211816;
b State Key Laboratory for Oxo Synthesis and Selective Oxidation, Center for Excellence in Molecular Synthesis, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics(LICP), Chinese Academy of Sciences, Lanzhou 730000

Received:2020-02-24 Revised:2020-05-08 Published:2020-05-15
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21702212, 21772208) and the Key Research Program of Frontier Sciences of Chinese Academy of Sciences (No. QYZDJSSW-SLH051).

Industrial processes of fixing carbon dioxide (CO₂) lag far behind the carbon emission generated by human activity. Since CO₂ is an abundant, non-toxic, and cost-effective one carbon source, it is highly desirable to develop methodologies on converting CO₂ into valuable products for sustainable purpose. Based on the mechanistic insight of CO₂ activation by transition-metal catalyst and organocatalyst, a variety of efficient asymmetric CO₂ chemical fixation processes have been developed in recent years. This review discusses the advances of enantioselective synthesis of small molecules by asymmetric catalytic reactions with CO₂. The interaction between catalyst, CO₂ and substrate has been elaborated aiming to inspire the design of new catalytic systems for asymmetric CO₂ transformation.

Key words: carbon dioxide, asymmetric catalysis, enantioselectivity, carboxylation, cyclization

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Guo Xiao, Wang Yazhou, Chen Jie, Li Gongqiang, Xia Ji-Bao. Recent Advances of CO₂ Fixation via Asymmetric Catalysis for the Direct Synthesis of Optically Active Small Molecules[J]. Chinese Journal of Organic Chemistry, 2020, 40(8): 2208-2220.

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不对称催化实现的二氧化碳固定直接合成光学活性小分子的最新进展

Recent Advances of CO₂ Fixation via Asymmetric Catalysis for the Direct Synthesis of Optically Active Small Molecules

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