Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (10): 2606-2624.DOI: 10.6023/cjoc201804009 Previous Articles     Next Articles

Special Issue: 荧光探针-生物传感合辑 有机超分子化学合辑



庞楚明a, 罗时荷a, 郝志峰b, 高健a, 黄召昊a, 余家海a, 余思敏a, 汪朝阳a   

  1. a 华南师范大学化学与环境学院 教育部环境理论化学重点实验室 广州 510006;
    b 广东工业大学轻工化工学院 广州 510006
  • 收稿日期:2018-04-05 修回日期:2018-05-15 发布日期:2018-06-06
  • 通讯作者: 汪朝阳,;郝志峰,;
  • 基金资助:


Synthesis and Fluorescent Sensing Application of Porous Organic Polymer Materials

Pang Chuminga, Luo Shihea, Hao Zhifengb, Gao Jiana, Huang Zhaohaoa, Yu Jiahaia, Yu Simina, Wang Zhaoyanga   

  1. a Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, School of Chemistry and Environment, South China Normal University, Guangzhou 510006;
    b School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006
  • Received:2018-04-05 Revised:2018-05-15 Published:2018-06-06
  • Contact: 10.6023/cjoc201804009;
  • Supported by:

    Project supported by the Undergraduates Innovation Project of South China Normal University (No. 20181415), the Natural Science Foundation of Guangdong Province (No. 2014A030313429), the Guangzhou Science and Technology Project Scientific Special (No. 201607010251), the Applied Science and Technology Research and Development Special Foundation of Guangdong Province (No. 2016B090930004) and the Guangdong Provincial Science and Technology Project (No. 2017A010103016).

Porous organic polymer fluorescence materials have the characteristics of high porosity and outstanding fluorescence properties. The function of fluorescence sensing is given when the skeleton has binding sites with specific analytes, such as nitroaromatic explosives (NAEs), metal ions, anions, gases, organic solvents, etc. In this paper, according to the different types of porous organic polymer materials (POPs), namely the amorphous porous organic polymer materials, crystal porous metal organic framework materials (MOFs) containing coordination bond, and crystal covalent organic framework materials (COFs), the new progress of the POPs fluorescence materials in recent years is reviewed. Especially, the design and synthesis based on functional organic molecules, and their fluorescence sensing applications, are introduced in details. In the future, continuing to design new types of fluorescent COFs from the molecular level is a development direction of highly efficient and recyclable fluorescence chemosensors for detecting NAEs, metal ions, anions, etc.

Key words: porous organic polymer materials, design and synthesis, fluorescent sensing application, detection of nitroaromatic explosives, crystal covalent organic framework materials