Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (2): 339-350.DOI: 10.6023/cjoc201909024 Previous Articles     Next Articles

光催化有机物偶联/芳构化放氢反应研究进展

陈锋, 陈浩, 吴庆安, 罗书平   

  1. 浙江工业大学化学工程学院 绿色化学合成技术国家重点实验室培育基地 杭州 310014
  • 收稿日期:2019-09-16 修回日期:2019-10-18 出版日期:2020-02-25 发布日期:2019-11-01
  • 通讯作者: 罗书平 E-mail:Luoshuping@zjut.edu.cn
  • 基金资助:
    国家自然科学基金(No.21376222)和浙江省自然科学基金(No.LY18B060011)资助项目.

Progress on the Photocatalytic Organic Hydrogen-Evolution Coupling/Aromatization Reaction

Chen Feng, Chen Hao, Wu Qing'an, Luo Shuping   

  1. State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014
  • Received:2019-09-16 Revised:2019-10-18 Online:2020-02-25 Published:2019-11-01
  • Supported by:
    Project supported by the National Natural Science Foundation of China (No. 21376222) and the Natural Science Foundation of Zhejiang Province (No. LY18B060011).

The photocatalytic redox reactions have been widely concerned in organic chemistry due to their green, efficiency and safety. In this review, the cross-coupling/aromatization reactions are described based on photocatalytic organic hydrogen-evolution, which can be used to build organic carbon-carbon and carbon-heteroatom bonds by using a photocatalyst/catalyst dual catalytic system. Hydrogen is the only by-product in these reactions. The system and catalytic mechanisms of organic photocatalytic redox reaction are highlighted.

Key words: photocatalysis, organic hydrogen-evolution reaction, coupling reaction, aromatization reaction