Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (8): 2232-2253.DOI: 10.6023/cjoc202003051 Previous Articles     Next Articles

聚集诱导发光有机氟化合物的研究进展

秦成远a, 刘威a, 聂永a, 高迎a, 苗金玲b, 李天瑞a, 蒋绪川a   

  1. a 济南大学智能材料与工程研究院 济南 250022;
    b 济南大学化学化工学院 山东省氟化学化工材料重点实验室 济南 250022
  • 收稿日期:2020-03-22 修回日期:2020-05-09 出版日期:2020-08-25 发布日期:2020-05-28
  • 通讯作者: 聂永, 蒋绪川 E-mail:chm_niey@ujn.edu.cn;ism_jiangxc@ujn.edu.cn
  • 基金资助:
    山东省自然科学基金(No.ZR2017LB008)、济南大学科技计划(No.XKY1906)和山东莘纳智能新材料有限公司资助项目.

Advances in Organofluorine Compounds with Aggregation-Induced Emission

Qin Chengyuana, Liu Weia, Nie Yonga, Gao Yinga, Miao Jinlingb, Li Tianruia, Jiang Xuchuana   

  1. a Institute for Smart Materials&Engineering, University of Jinan, Jinan 250022;
    b School of Chemistry and Chemical Engineering, Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical Materials, University of Jinan, Jinan 250022
  • Received:2020-03-22 Revised:2020-05-09 Online:2020-08-25 Published:2020-05-28
  • Supported by:
    Project supported by the Natural Science Foundation of Shandong Province (No. ZR2017LB008), the Science and Technology Program of University of Jinan (No. XKY1906) and the Shandong Shenna Smart Advanced Materials Co., Ltd.

Aggregation-induced emission (AIE) compounds have attracted much attention due to their important potential applications in biological and chemical sensing, luminescent materials, display and other areas. As an important class of functional molecules, organofluorine compounds have been widely studied in areas such as organic chemitry and materials chemistry. The organofluorine compounds with AIE properties are summarized and classified. The currently reported AIE organofluorine compounds include the fluorinated tetraphenylethene (TPE) derivatives, 9,10-distyrylanthracene (DSA) derivatives, cyanostilbene derivatives, distyrylbenzene derivatives, fluorinated polymers, carborane clusters, room temperature phosphorescent molecules, and some other fluorinated structures. With fluorine atoms in the structures, the stability of the resulting AIE compounds is generally improved, and fluorine atoms often participate in the intermolecular interactions leading to significant changes in the structure of the aggregation state, and hence changes in luminescence properties, for example, emission enhancement, bathochromism or hypsochromism of the emissions, improvement of the emission quantum yield and lifetime. The prospects of the future study are also discussed.

Key words: aggregation-induced emission, organic luminescent material, organofluorine compound, stimuli responsiveness