Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (2): 504-520.DOI: 10.6023/cjoc202007015 Previous Articles     Next Articles



秦成远a, 苗金玲b, 聂永a,*(), 刘威a, 高迎a, 李天瑞a, 蒋绪川a,*()   

  1. a 济南大学智能材料与工程研究院 济南 250022
    b 济南大学化学化工学院 山东省氟化学化工材料重点实验室 济南 250022
  • 收稿日期:2020-07-05 修回日期:2020-08-18 发布日期:2020-09-16
  • 通讯作者: 聂永, 蒋绪川
  • 作者简介:
    * Corresponding authors. E-mail: ;
  • 基金资助:
    山东省自然科学基金(ZR2017LB008); 山东省自然科学基金(ZR2020MB001); 济南大学科技计划(XKY1906); 山东莘纳智能新材料有限公司资助项目

Advances in Fluorinated Organometallic Complexes with Aggregation-Induced Emission Characteristics

Chengyuan Qina, Jinling Miaob, Yong Niea,*(), Wei Liua, Ying Gaoa, Tianrui Lia, Xuchuan Jianga,*()   

  1. a Institute for Smart Materials & Engineering, University of Jinan, Jinan 250022
    b Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical Materials, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022
  • Received:2020-07-05 Revised:2020-08-18 Published:2020-09-16
  • Contact: Yong Nie, Xuchuan Jiang
  • Supported by:
    the Natural Science Foundation of Shandong Province(ZR2017LB008); the Natural Science Foundation of Shandong Province(ZR2020MB001); the Science and Technology Program of University of Jinan(XKY1906); Shandong Shenna Smart Advanced Materials Co.,Ltd.

In recent years, the compounds with aggregation-induced emission (AIE) characteristics have received increasing attention because they exhibit much higher luminescence quantum yields in aggregation or solid states than in solution. Due to the presence of the fluorine atom(s), fluorinated functional compounds generally have unique structures, and physical, chemical and biological properties. Herein, the luminescent organometallic complexes with AIE characteristics having fluorine-containing ligands are summarized, according to the types of central metal atoms and ligands. Such organometallic complexes are mainly those of iridium, platinum and gold, with potential applications in light-emitting devices, chemical sensing, cell imaging and data storage, etc. The prospects of the relevant studies are also discussed.

Key words: aggregaion-induced emission, fluorine, cyclometalated complex, organometallic complex, phosphorescence