Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (10): 3880-3891.DOI: 10.6023/cjoc202105053 Previous Articles     Next Articles

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过渡金属催化的C—P键活化

张凤萍, 栾玉新*(), 叶萌春*()   

  1. 南开大学化学学院 元素有机化学国家重点实验室 天津 300071
  • 收稿日期:2021-05-31 修回日期:2021-07-12 发布日期:2021-07-26
  • 通讯作者: 栾玉新, 叶萌春
  • 基金资助:
    国家自然科学基金(21871145); 国家自然科学基金(91856104); 天津市自然科学基金(19JCZDJC37900)

Transition Metal-Catalyzed C—P Bond Activation

Fengping Zhang, Yuxin Luan(), Mengchun Ye()   

  1. State Key Laboratory and Institute of Elemento-organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071
  • Received:2021-05-31 Revised:2021-07-12 Published:2021-07-26
  • Contact: Yuxin Luan, Mengchun Ye
  • Supported by:
    National Natural Science Foundation of China(21871145); National Natural Science Foundation of China(91856104); Natural Science Foundation of Tianjin City(19JCZDJC37900)

Transition metal-catalyzed C—P bond activation provides an ecomomical and high-efficient route for the synthesis of organic phosphine compounds, and has received increasing attention in recent years. Owing to high bond energy of C—P bond and strong coordinative ability of P atom, the activation of C—P bond has been a fomidable challenge. Relying on substrate-preactivation and various catalysts, great progress has been achieved. This review will give a summary of this field, and according to different mechanisms of C—P bond activation and strategies of substrate pre-activation, a detailed description on reaction type, development, characteristics and mechanism will be made.

Key words: organophosphines, transition metal, C—P bond activation