Synthesis and Anion Recognition Properties of Receptors of 4'-Sulfonylhydrazone Benzo-15-crown-5

Abstract

A new series of crowned sulfonylhydrazone derivatives 3a～3h have been synthesized by condensation of aromatic aldehydes with (benzo-15-crown-5)-4'-sulfohydrazide (2) and characterized by elemental analysis, IR, ¹H NMR, ¹³C NMR and MS spectra. Compound 2 was synthesized from benzo-15- crown-5 via sulphonation and hydrazinolysis. The UV-Vis data indicated that the receptors 3d, 3e and 3h bearing phenolic hydroxy groups can act as selective sensors for basic anions.

Key words: benzo-15-crown-5, sulphonation, recognition, crown ether

Cite this article

WEI Tai-Bao,WANG Jun,LUO Rong,ZHANG You-Ming*. Synthesis and Anion Recognition Properties of Receptors of 4'-Sulfonylhydrazone Benzo-15-crown-5[J]. Chin. J. Org. Chem., 2007, 27(11): 1381-1385.

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4'-磺酰腙苯并-15-冠-5的合成及阴离子识别研究