三维氮掺杂碳纳米带的制备及其在锂硫电池中的应用

doi:10.6023/A16080434

化学学报 ›› 2017, Vol. 75 ›› Issue (2): 225-230.DOI: 10.6023/A16080434 上一篇下一篇

所属专题：先进电池材料

研究论文

三维氮掺杂碳纳米带的制备及其在锂硫电池中的应用

李宛飞^a, 马倩^a, 郑召召^a, 张跃钢^a,b

a 中国科学院苏州纳米技术与纳米仿生研究所国际实验室苏州 215123;
b 清华大学物理系北京 100084

投稿日期:2016-08-25 修回日期:2016-12-05 发布日期:2016-12-05
通讯作者: 张跃钢,E-mail:ygzhang2012@sinano.ac.cn;Tel:0512-62872772 E-mail:ygzhang2012@sinano.ac.cn
基金资助:
项目受国家自然科学基金（Nos.21433013，51402345，21403287）和苏州市科技计划项目（Nos.ZXG2013002，SYG201532）资助.

Preparation of Three-dimensional Nitrogen-doped Carbon Nanoribbon and Application in Lithium/Sulfur Batteries

Li Wanfei^a, Ma Qian^a, Zheng Zhaozhao^a, Zhang Yuegang^a,b

a i-Lab, Suzhou Institute of Nano-Tech and Nano-bionics, Chinese Academy of Sciences, Suzhou, Jiangsu, 215123;
b Department of Physics, Tsinghua University, Beijing, 100084

Received:2016-08-25 Revised:2016-12-05 Published:2016-12-05
Contact: 10.6023/A16080434 E-mail:ygzhang2012@sinano.ac.cn
Supported by:
Project supported by the Natural Science Foundation of China (Nos. 21433013, 51402345, 21403287), and the Suzhou Science and Technology Development Program (Nos. ZXG2013002, SYG201532).

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1. 三维氮掺杂碳纳米带的制备及其在锂硫电池中的应用.PDF(1462KB)

摘要/Abstract

锂硫电池凭借其高的理论能量密度（2600 W·h·kg^-1）、丰富廉价的材料来源、且对环境友好等优势，而引起了人们的广泛关注.然而，锂硫电池活性物质导电性差、多硫化物易溶于有机电解液等问题所导致的硫正极倍率性能和循环稳定性差，仍然是困扰锂硫电池发展的挑战性难题.我们设计并以廉价易得的小分子化合物对苯二酚和甲醛为原料，通过缩聚反应、与氧化石墨烯原位复合、高温氮化制备了一类新型氮掺杂的碳纳米带固硫载体材料（NCNB-NG）.通过NCNB-NG复合纳米硫进一步得到的碳-硫复合正极材料（S@NCNB-NG）表现出更优异的倍率性能和循环稳定性，这主要得益于该碳质载体独特的微结构以及改善的导电性.

关键词: 锂硫电池, 碳, 氮掺杂, 纳米带, 三维

Lithium/sulfur (Li-S) batteries have recently attracted intensive research interests due to their high theoretical specific energy of 2600 W·h·kg^-1. However, the poor electronic conductivity of sulfur and the high solubility of polysulfides in organic electrolytes lead to poor cycling stability and rate capability. Herein, we report a three-dimensional (3D) nanocomposite network made from nitrogen-doped carbon nanoribbon (NCNB) and nitrogen-doped graphene (NG), which has a high electronic conductivity and can serve as a conductive matrix and a sulfur immobilizer for the sulfur cathode. The NCNB is prepared by thermal nitridation of a unique 3D phenolic resin (PHF) isolated from the polycondensation reaction of 1,4-hydroquinone and formaldehyde. The N content of NCNB-NG can reach as high as 9.7 wt%. Although three types of N bonding geometries, including pyridinic N, pyrrolic N, and graphitic N, are identified in the NCNB-NG composites, we found the pyridinic N is dominant, which facilitates the trapping of intermediate lithium polysulfides. The sulfur was loaded on NCNB-NG by using a Na₂S₂O₃ solution as sulfur source. The scanning electron microscope (SEM) images show that almost no large S particle can be observed in the as-prepared S@NCNB-NG nanocomposites, suggesting a uniform coating of S on the NCNB-NG networks. The transmission electron microscopic (TEM) images and the elemental mapping by Energy-Dispersive X-ray (EDX) analysis also show that nano-sized S particles are uniformly distributed on the NCNB-NG matrix. The as-obtained S@NCNB-NG cathode can deliver a high specific capacity of 1338 mA·h·g^-1 at 0.05 C with about 80% S utilization. It also exhibits excellent rate capability and good cycle stability with a retained specific capacity of 556 mA·h·g^-1 after 300th cycles. These performances are much higher than the control samples using the S@NCNB and the S@PHF nanocomposites as cathodes. The improved performance can be attributed to the unique microstructure and the improved electronic conductivity of the NCNB-NG matrix.

Key words: lithium/sulfur battery, carbon, N-doped, nanoribbon, three-dimensional

引用此文

李宛飞, 马倩, 郑召召, 张跃钢. 三维氮掺杂碳纳米带的制备及其在锂硫电池中的应用[J]. 化学学报, 2017, 75(2): 225-230.

Li Wanfei, Ma Qian, Zheng Zhaozhao, Zhang Yuegang. Preparation of Three-dimensional Nitrogen-doped Carbon Nanoribbon and Application in Lithium/Sulfur Batteries[J]. Acta Chim. Sinica, 2017, 75(2): 225-230.

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三维氮掺杂碳纳米带的制备及其在锂硫电池中的应用

Preparation of Three-dimensional Nitrogen-doped Carbon Nanoribbon and Application in Lithium/Sulfur Batteries

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