化学学报 ›› 1994, Vol. 52 ›› Issue (1): 76-82. 上一篇    下一篇

研究论文

两种喹啉类药物在水/硝基苯界面循环伏安研究

王 明;俞泽穆;汪尔康   

  1. 中国科学院长春应用化学研究所;中国科学院电分析化学开放研究实验室
  • 发布日期:1994-01-15

Cyclic voltammetric study of quinine derivatives transfer across the water/nitrobenzene interface

WANG;YU ZEMU;WANG ERKANG   

  • Published:1994-01-15

本文用循环伏安法研究了盐酸喹啉和8-羟基喹啉配合质子在水/硝基苯界面的转移过程, 讨论了水相pH值对其转移行为的影响, 探讨了有关转移过程的机理, 测定并计算了有关热力学参数。

关键词: 硝基苯, 界面, 羟基喹啉类, 循环伏安法, 质子转移, 热力学参数, 盐酸喹啉

Quinine derivatives, quinine hydrochloride and 8-hydroxyquinoline, transfer across the water/nitrobenzene interface was studied by cyclic voltammetry. The effect of solution acidity on the transfer behaviour was observed. Transfer mechanism was discussed and parameters related to interfacial behavior were estimated.

Key words: NITROBENZENE, INTERFACES, HYDROXY QUINOLINES, CYCLOVOLTAMGRAPH, THERMODYNOMICS PARAMETER

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