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化学学报
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化学学报 ›› 2002, Vol. 60 ›› Issue (5): 847-853. 上一篇    下一篇

研究论文

5-位取代吡唑啉化合物的发光行为及其在电致发光领域中的应用

马昌期;张联齐;李晓卉;王雪松;张宝文;曹怡;汪东明;蒋雪茵;张志林   

  1. 中国科学院理化技术研究所.北京(100101);上海大学材料科学与工程学院.上 海(201800);清华大学化学系.北京(100084)
  • 发布日期:2002-05-15

The Luminescent Properties of 5-Substituted 2-Pyrazoline and Application in Electroluminescent Device

Ma Changqi;Zhang Lianqi;Li Xiaohui;Wang Xuesong;Zhang Baowen;Cao Yi;Wang Dongming;Jiang Xueyin;Zhang Zhilin;Zhang Deqiang;Qiu Yong   

  1. Technical Institute of Physics and Chemistry, Chinese Academic of Sciences.Beijing(100101);School of Material Science & Engineering, Shanghai University.Shanghai(201800);Department of Chemistry, Tsinghua University.Beijing(100084)
  • Published:2002-05-15

PDF

444

被引次数

26 | 10

合成了一系列5位不同取代的2－吡唑啉化合物，研究了取代基对吡唑啉化合物 物理性质的影响。结果表明，在吡唑啉化合物的5位引入稠环取代基提高了吡唑啉 化合物的熔点；同时，5位取代基的电位性质还影响着化合物的发光行为。DSC差热 分析结果给出1，3－二苯基－5－（9－菲基）－2－吡唑啉（TAP7）的玻璃化温度 (T_g)为96 ℃；并研究了其在电致发光器件上的应用性能。结果表明TAP7是一种具 有高热稳定性的空穴传输及蓝光发光材料。

关键词: 吡唑啉, 电致发光, 热稳定性, 发光材料, 示差扫描量热法

A series of 5-substituted 2-pyrazoline derivatives were synthesized and their physical properties were measured. The results indicate that the introduction of bulky groups into the pyrazoline ring increases the glass transition temperature (T_g) of the compounds and changes the luminescent mechanism of the compounds. Differential scanning calorimetry (DSC) shows that the new pyrazoline derivative, 1, 3- diphenyl-5-(9-phenanthrenyl)-2-pyrazoline (TAP7) has high T_g of 96 ℃. The electroluminescent properties of this compound were measured. It is demonstrated that TAP7 is a good hole transport material and blue electroluminescent material with high thermal stability.

Key words: PYRAZOLINE, ELECTROLUMINESCENCE, THERMAL STABILITY, LUMINESCENT MATERIALS, DSC

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