关键词: 二氧化硅, 氧化铝, 氯化钠, 过氧化氢, 体系, 沸石, 薄膜, 方钠石, 光致变色, 分子筛

The membranes of zeolite ANA (analcime) and zeolite SOD (sodalite) were synthesized in the reactant system of Na_2O-SiO_2-Al_2O_3-NaCl- H_2O using water glass and boehmite as the raw materials on the support of cordierite and glass, respectively. A study has been made of the influence of the molar ratio of H_2O/SiO_2 in the reactant, the reaction period, and the multiple synthesis on the crystallization of the membrane. The crystalline phase and the morphology of the membrane synthesized were characterized with XRD SEM and EDX. The pervaporation of 95%(wt.) ethanol/5%(wt.) water through analcime membrane supported on cordierite showed the separation selectivity preference to water molecules, indicating that the separation process occurs in the pores of ANA zeolite inter-crystallites. Non-stoichiometric NaCl was found in SOD membrane supported on glass, and the photochromic effect exhibited after irradation with X-ray radiation.

Key words: SILICON DIOXIDE, ALUMINIUM OXIDE, SODIUM CHLORIDE, HYDROGEN PEROXIDE, SYSTEMS, ZEOLITE, THIN FILMS, SODALITE, PHOTOCHROMISM, MOLECULAR SIEVE