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化学学报
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化学学报 ›› 2002, Vol. 60 ›› Issue (6): 1058-1064. 上一篇    下一篇

研究论文

线型1,2-邻二萘醌-1-肟(1-nqo)钌配合物的合成

刘晓霞;孙克;黄永德;朱建军;张宝砚   

  1. 东北大学化学系,沈阳(110004);香港大学化学系.香港
  • 发布日期:2002-06-15

Synthesis of Rod-like Ruthenium Complexes of 1,2-Naphthoquinone-1- oxime

Liu Xiaoxia;Sun Ke;Wong Wingtak;Niu Jianjun;Zhang Baoyan   

  1. Department of Chemistry, Northeastern University,Shenyang(110004);Department of Chemistry, The University of Hong Kong.Hong Kong
  • Published:2002-06-15

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被引次数

7 | 1

报道了含C_(16)长碳链线型1,2-邻二萘醌-1-肟(1-nqo)钌配合物trans-，cis- 及cis-，cis-[Ru(1-nqo)_2(CO)(spy)] (3)及(4)含C_(18)长碳链线型1-nqo钌配合 物cis-，cis-[Ru(1-nqo)_2(CO)(opy)] (5)，trans-，trans-[Ru(1-nqo)_2(opy) _2] (6)的合成。利用红外、FAB质谱、核磁共振氢谱及紫外-可见吸收光谱表征配 合物的结构，利用~1H-~1H偶合二维核磁技术对核磁共振峰进行指认。

关键词: 钌络合物, 萘醌, 羰基化合物, 取代反应, 肟, 红外分光光度法, 质子磁共振谱法

By decarbonylated substitution reactions, rod-like ruthenium complexes of 1,2-naphthoquinone-1-oxime (1-nqo) are synthesized as trans-, cis- and cis-, cis-[Ru(1-nqo)_2(CO)(spy)] (3) and (4) which containing C_(16) long alkyl chains in the molecules, cis-, cis-[Ru(1- nqo)_2(CO)(opy)] (5) and trans-, trans-[Ru(1-nqo)_2(opy)_2] (6) which containing C_(18) long alkyl chains in the molecules. The complexes are characterized by IR, FAB MS, - ~1H-~1H COSY NMR and UV-visible spectra.

Key words: RUTHENIUM COMPLEX, NAPHTHOQUINONE, CARBONYL COMPOUNDS, SUBSTITUTION REACTION, OXIME, IR, 1HNMR

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