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化学学报
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化学学报 ›› 2007, Vol. 65 ›› Issue (21): 2428-2432. 上一篇    下一篇

研究论文

聚合物模板辅助镍微球的水热制备

王炳喜*，林航，左正笏   

  1. (福州大学材料科学与工程学院 福州 350002)
  • 投稿日期:2007-07-18 修回日期:2007-09-26 发布日期:2007-11-14
  • 通讯作者: 王炳喜

Nickel Microspheres Prepared by Hydrothermal Process Assisted with Polymer Template

WANG Bing-Xi*; LIN Hang; ZUO Zheng-Hu   

  1. (College of Materials Science and Engineering, Fuzhou University, Fuzhou 350002)
  • Received:2007-07-18 Revised:2007-09-26 Published:2007-11-14
  • Contact: WANG Bing-Xi

PDF

877

被引次数

5

以三嵌段共聚物HO(CH2CH2O)20(CH2CH(CH3)O)70(CH2CH2O)20H (P123)为模板剂, 次亚磷酸钠为还原剂, 水热制备了微米级镍微球. 采用X射线衍射(XRD)、扫描电镜(SEM)和振动样品磁强计(VSM)对产物进行表征. 结果表明, 镍微球由纳米级的镍微晶组成, 其中至少部分微球存在空心结构. 微球的尺寸随着前驱体溶液pH值的增加而减小, 其聚集成链的程度随着水热温度的上升而增强. 120和220 ℃水热合成微球的直径范围、平均微晶尺寸和矫顽力分别是1.5～4.5和0.8～4.5 μm, 16.0和14.2 nm, 以及91.5和66.1 Oe.

关键词: 镍微球, 嵌段共聚物, 水热法

Nickel microspheres have been prepared by a hydrothermal process with a template of triblock copolymer HO(CH2CH2O)20(CH2CH(CH3)O)70(CH2CH2O)20H (P123) and a reductant of sodium hy-pophosphite. The prepared products were characterized with X-ray diffraction (XRD), scanning electron mi-croscopy (SEM) and vibrating sample magnetometer (VSM). Results show that the nickel microspheres are composed of nickel nanocrystals, and at least a part of them possess hollow structures. The size of the mi-crospheres decreases with an increase in pH value of the precursor solution, and their aggregation degree to form chainlike assemblies rises with the elevation of temperature. Two kinds of microspheres prepared at 120 and 220 ℃ have diameter ranges of 1.5～4.5 and 0.8～4.5 μm, and consist of nanocrystals with aver-age sizes of 16.0 and 14.2 nm, and their coercivities are 91.5 and 66.1 Oe, respectively.

Key words: nickel microsphere, block polymer, hydrothermal process