化学学报 ›› 1996, Vol. 54 ›› Issue (9): 917-921. 上一篇    下一篇

研究论文

不同环境介质中芘的三维荧光光谱研究

鄢远;许金钧;陈国珍   

  1. 厦门大学化学系
  • 发布日期:1996-09-15

Study on three-dimensional fluorescence spectra of pyrene in various environments

YAN YUAN;XU JINGOU;CHEN GUOZHEN   

  • Published:1996-09-15

本文首次运用三维荧光光谱研究芘在不同环境介质中的荧光特性, 揭示芘的F3/F4反映的是环境有序性介质的形成, 而不是所处环境极性大小的一个量度,F1/F3才是其所处环境极性大小的一个量度, 结果显示芘的三维荧光光谱可以更好地对环境性质进行研究, 将进一步扩大芘的应用范围。

关键词: 胶束, 荧光特性, 芘, 荧光探针, 三维荧光光谱

The fluorescent properties of pyrene monomer in various environments, such as β-CD, CTAB, SDS and glycerl solutions, have first been studied by three-dimensional fluorescence spectrometry. The results show that the F~3/F~4 ratio, namely the relative intensity of peak 3 (λ~e~x/λ~e~m=340/378nnm) to peak 4 (λ~e~x/λ~e~m=340/396nm), can be used to estimate the formation of organized medium, but not the polarity of environment. Only F~1/F~3 ratio, the relative intensity of peak 1 (λ~e~x/λ~e~m=275/378nm) to peak 3, can be used as the probe for the polarity of environment. The three-dimensional fluorescence spectra of pyrene have superiority in studying the properties of environment.

Key words: MICELLE, FLUORESCENCE CHARACTERISTIC, PYRENE, FLUORESCENCE PROBE

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