化学学报 ›› 2001, Vol. 59 ›› Issue (5): 774-779. 上一篇    下一篇

研究论文

CXN天然沸石的研究Ⅲ.新型 LiCl/H-STI主/客体固电解质的制 备与表征

邹静;莫蓓红;龙英才   

  1. 复旦大学化学系.上海(200433)
  • 发布日期:2001-05-15

Studies on CXN natural zeolite 3: Preparattion and characterization of noval LiCl/H-STI guest /host solid electrolute

Zou Jing;Mo Beihong;Long Yingcai   

  1. Fudan Univ, Dept Chem.Shanghai(200433)
  • Published:2001-05-15

利用自发热扩散法,将易潮解流失的LiCl(客体)固全到CXN沸石改所得的H-STI沸石(主体)上,形成新型主/客体材料,粉未XRD,SEM,FT-IR和TG/STA等方法表征显示LiCl已经分散到H-STI孔道中,实现了客体的稳定化,其分散阈值0.14g/g。负载量为阈值的样品在绝湿条件下的电导率比主体H-STI提高了四个数量级,是一种良好的固体电解质。

关键词: 沸石, 电解质, 氯化锂, 电导率, X射线衍射分析, 扫描电子显微镜, 付里叶变换, 红外分光光度法

By calcination at 250℃for 16h, LiCl can be highly dispersed into the channels of H-STI prepared from natural CXNB( STI type) zelite discovered in chaina to form a novel guest /host material. XRD, SEM, FT-IR and DTA analysis show that LiCl has been loaded and stabilized in the channels of H-sti. The threshold of LiCl loaded in H-STI is 0. 14g.g, which has been cinfirmed by AC-impedance mesure ments. A sample of LiCl/H-STI with 0.14g/g loading found to possess the highest conductivity, which is four orders of magnitude higher than that of the host (H-STI). This fact indicates that LiCl/H-STI is a promising solid electrolyte.

Key words: ZEOLITE, ELECTROLYTE, LITHIUM CHLORIDE, ELECTRICAL CONDUCTIVITY, X-RAY DIFFRACTION ANALYSIS, SCANNING ELECTRON MICROSCOPES, FOURIER TRANSFORM, INFRARED SPECTROPHOTOMETRY

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