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化学学报
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化学学报 ›› 2011, Vol. 69 ›› Issue (20): 2465-2470. 上一篇    下一篇

研究论文

以反丁烯二酰氯桥联的10,15,20-三(对-氯代苯基)卟啉二联体及其配合物的合成与性质研究

孙园园1，连文慧1，王建成2，王彬彬1，单凝1，于连香1，于苗*,1，师同顺*,1   

  1. (1吉林大学化学学院 长春 130021)
    (2吉林大学机械科学与工程学院 长春 130025)
  • 投稿日期:2011-01-22 修回日期:2011-04-03 发布日期:2011-06-07
  • 通讯作者: 师同顺 E-mail:shitongshun@jlu.edu.cn
  • 基金资助:

    国家自然科学基金

Synthesis and Characterization of (E)-2-Butenedioyl Dichlorid Bridge-linked 10,15,20-Tri(p-chlorophenyl)porphyrin Dimer and Its Complexes

Sun Yuanyuan1 Lian Wenhui1 Wang Jiancheng2 Wang Binbin1 Shan Ning1 Yu Lianxiang1 Yu Miao*,1 Shi Tongshun*,1   

  1. (1 College of Chemistry, Jilin University, Changchun 130021)
    (2 College of Mechanics, Jilin University, Changchun 130025)
  • Received:2011-01-22 Revised:2011-04-03 Published:2011-06-07
  • Contact: SHI Tong-Shun E-mail:shitongshun@jlu.edu.cn

PDF

1121

被引次数

9

用5-(对-羟基苯基)-10,15,20-三(对-氯代苯基)卟啉为原料合成了以反丁烯二酰氯桥连的10,15,20-三(对-氯代苯基)卟啉二联体及其Zn, Cu, Co, Mn配合物, 并用红外光谱、拉曼光谱、紫外光谱、质谱、核磁共振谱对其结构进行了表征. 利用分子荧光光谱和表面光电压对其光学性质进行了研究.

关键词: 卟啉, 反丁烯二酰氯, 二联体, 合成, 配合物, 荧光

The 10,15,20-tri(p-chlorophenyl)porphyrin dimer was synthesized with (e)-2-butenedioyl dichlorid as a bridge-linked reagent and its Zn, Cu, Co, Mn complexes were synthesized and characterized by means of IR, Raman, UV-Vis, MS, 1H NMR and 13C NMR. The optical properties were studied by fluorescence spectrometer and SPS (surface photovoltage spectroscopy).

Key words: porphyrin, (e)-2-butenedioyl dichlorid, dimer, synthesis, complex, fluorescence