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化学学报
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化学学报 ›› 2012, Vol. 70 ›› Issue (02): 190-194.DOI: 10.6023/A1105186 上一篇    下一篇

研究论文

新型树状单分子磷-氮膨胀阻燃剂的合成及阻燃性能研究

卢林刚a, 王晓b, 杨守生b, 董希琳a, 唐凯a, 余厚珺b   

  1. a 中国人民武装警察部队学院科研部 廊坊 065000;
    b 中国人民武装警察部队学院消防工程系 廊坊 065000
  • 投稿日期:2011-05-18 修回日期:2011-09-09 发布日期:2012-02-25
  • 通讯作者: 卢林刚 E-mail:wjxylulingang@sohu.com

Synthesis and Application of Novel Arborescent Monomolecular P-N Intumescent Flame Retardant

Lu Linganga, Wang Xiaob, Yang Shoushengb, Dong Xilina, Tang Kaia, Yu Houjunb   

  1. a Department of Science and Technology, Chinese People's Armed Police Force Academy, Langfang 065000;
    b Department of Fire Protection Engineering, Chinese People's Armed Police Force Academy, Langfang 065000
  • Received:2011-05-18 Revised:2011-09-09 Published:2012-02-25

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1411

被引次数

33 | 9

以六氯环三磷腈、对羟基苯甲醚、新戊二醇以及三氯氧磷等为原料, 合成一种新型树状单分子磷-氮膨胀阻燃剂六(4-(5,5-二甲基-1,3-二氧杂环己内磷酸酯基苯氧基))环三磷腈(Ⅵ). 标题化合物结构经IR、MS 及1H NMR 证实. 热失重分析表明标题化合物具有较高的热稳定性和良好的成炭性, 氮气氛下的起始分解温度为270 ℃, 600 ℃时炭残余量达45.2%. 实验表明, 标题化合物对环氧树脂呈现出良好的阻燃效果.

关键词: 膨胀阻燃剂, 合成, 热分解, 环氧树脂

The novel arborescent monomolecular P-N intumescent flame retardant hexalis-(4-(5,5-dimehtyl-1,3-dioxaphospho-rinanyl-2-oxy-phosphate-ester-phenoxy))-cyclotriphosphazene (Ⅵ) was synthesized via hexachlorotriphosphazene, 4-methoxyphenol, neopentyl alcohol and phosphous oxychloride by a three step reaction and its structure was identified and studied by FT-IR, 1H NMR and MS analyses. The termogravimetry showed that the novel flame retardant had high thermal stability and excellent char-forming ability. The beginning temperature of the compound VI decomposition was 270 ℃, and the char yield was about 45.2% at 600 ℃ in N2. The results demonstrated that the novel arborescent P-N intumescent flame retardant was effective on the flame retardancy of epoxy resin.

Key words: intumescent flame retardant, synthesis, thermal decomposition, epoxy resin