化学学报 ›› 2013, Vol. 71 ›› Issue (03): 381-386.DOI: 10.6023/A12090707 上一篇    下一篇

研究论文

实验和理论研究石墨烯氧化物的铁电性

孔祥恺a, 陈乾旺a,b   

  1. a 合肥微尺度物质科学国家实验室 中国科学技术大学材料科学与工程系 合肥 230026;
    b 中国科学院合肥物质科学研究院 合肥 230031
  • 投稿日期:2012-09-24 发布日期:2013-01-09
  • 通讯作者: 陈乾旺 E-mail:cqw@ustc.edu.cn
  • 基金资助:

    项目受国家自然科学基金(Nos.21071137,U1232211)资助.

Experimental and Theoretical Investigations on the Ferroelectricity of Graphene Oxides

Kong Xiangkaia, Chen Qianwanga,b   

  1. a Hefei National Laboratory for Physical Sciences at Microscale and Department of Materials Science & Engineering, University of Science and Technology of China, Hefei 230026, China;
    b Hefei Institutes of Physical Sciences, Chinese Academy of Sciences, Hefei 230031, China
  • Received:2012-09-24 Published:2013-01-09
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21071137, U1232211).

基于独特的结构和性质, 石墨烯在很多领域都表现出了巨大的潜力. 作为制备石墨烯的主要母体材料, 石墨烯氧化物在室温条件下被观测到具有弱的铁电性. 石墨烯氧化物的表面和边界上会存在大量的羟基, 这些羟基有序重复排列而构成了一维的氢键链, 这些有序氢键链可能是石墨烯氧化物呈现铁电性能的主要原因.

关键词: 铁电性, 石墨烯, 石墨烯氧化物, 氢键

Graphene shows promise as a functional material in wide fields owing to its unique structures and properties. Here, as its parent material, graphene oxides have been observed exhibiting weak ferroelectric properties at room temperature. It is found that the one-dimensional hydrogen-bond chains generated by hydroxyls arranged in an orderly repeating pattern may play the key role in the electric ordering and may be responsible for this novel property of graphene oxide nano-ribbons.

Key words: ferroelectricity, graphene, graphene oxides, hydrogen-bond