Acta Chimica Sinica ›› 1993, Vol. 51 ›› Issue (7): 697-701. Previous Articles     Next Articles

Original Articles

高效毛细管区带电泳二肽类组分迁移行为的研究

陈农;王磊;张玉奎;卢佩章   

  1. 中国科学院大连化学物理研究所;中国科学院国家色谱研究分析中心
  • 发布日期:1993-07-15

Investigation on teh electrophoretic behaviour of dipeptides in high performance capillary zone electrophoresis

CHEN NONG;WANG LEI;ZHANG YUKUI;LU PEIZHANG   

  • Published:1993-07-15

The factors influencing the migration reproducibility of dipeptides in HPCZE were discussed. Two migration parameters, migration time and relative migration time, were investigated as the functions of operation current and column temperature The relative migration time was proposed to be an index for peak identification in HPCZE. The effects of applied current and column temperature on migration time have been discussed. The linear correlation between lgtm and T-1 has been derived and has been explained based on the fundamental migration equation in HPCZE. The criteria of relative migration time which are independent of applied current and column temperature shows the characteristic constant for a specific column in HPCZE.

Key words: DIPEPTIDE, MIGRATION, CAPILLARY ZONE ELECTROPHORESIS

CLC Number: