Acta Chimica Sinica ›› 2001, Vol. 59 ›› Issue (11): 1961-1965. Previous Articles     Next Articles

Original Articles

用电泳沉积技术制备空心Silicalite-1沸石纤维

柯琛;杨武利;倪铮;唐颐;高滋   

  1. 复旦大学化学系.上海(200433);复旦大学高分子科学系和教育部聚合物分子工 程重点实验室
  • 发布日期:2001-11-15

Fabrication of hollow zeolite fibers by electrophoretic assembly of nanosilicalite-1

Ke Chen;Yang Wuli;Ni Zheng;Tang Yi;Gao Zi   

  1. Fudan Univ, Dept Chem.Shanghai(200433)
  • Published:2001-11-15

Hollow zeolite fibers (abbreviated as HZF) have been successfully fabricated using electrophoretic deposition (EPD) technique with carbon fibers as templates and nanosilicalite-1 as building blocks, followed by removal of the templates by calcinating the zeolite- coated carbon fibers. Dense and complete zeolite deposition on carbon fibers is an essential premise for the preparation of intact HZFs. The formation of zeolite coating depends largely on the applied voltages and the surface charge of nanozeolites, which can be adjusted by the pH of the colloidal solution. In addition, deposition time and colloidal solution concentration also influence the deposit process. The structure of calcined HZFs has been characterized by XRD and IR.

Key words: ELECTROPHORESIS, SEDIMENTATION, ZEOLITE, NANOPHASE MATERIALS, FIBERS

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