Covalently Chemical Functionalization of Multi-walled Carbon Nanotubes with Amino Porphyrins

Acta Chimica Sinica ›› 2008, Vol. 66 ›› Issue (10): 1228-1234. Previous Articles Next Articles

Original Articles

氨基卟啉共价化学修饰多壁碳纳米管

许兰兰¹，赵鸿斌*^,1,2，徐勇军²，王红科¹，刘传生²

(¹湘潭大学化学学院湘潭 411105)
(²东莞理工学院化学生物工程系东莞 523808)

投稿日期:2007-10-09 修回日期:2007-12-12 发布日期:2008-05-28
通讯作者: 赵鸿斌

Covalently Chemical Functionalization of Multi-walled Carbon Nanotubes with Amino Porphyrins

XU, Lan-Lan¹, ZHAO, Hong-Bin*^,1,2, XU, Yong-Jun², WANG, Hong-Ke¹, LIU, Chuan-Sheng²

(¹ College of Chemistry, Xiangtan University, Xiangtan 411105)
(² Faculty of Chemical Biotechnology, Dongguan University of Technology, Dongguan 523808)

Received:2007-10-09 Revised:2007-12-12 Published:2008-05-28
Contact: ZHAO, Hong-Bin

Abstract

5-(4-Aminophenyl)-10,15,20-triphenylporphyrin and its copper(II) complex were synthesized. Then through the covalently chemical reaction between the oxidized multi-walled carbon nanotubes (MWNT) and the amino porphyrins, the composites were gotten. The chemical properties of the resultant products were characterized by FT-IR, finding the amidation reactions in the composites. Strong intramolecular interaction between the amino porphyrins and MWNT was found from UV-Vis absorption and fluorescence spectroscopy. The morphology of the functionalized MWNT was also observed using transmission electron microscopy, revealing that the amino porphyrins were attached to the sidewalls of MWNT.

Key words: amino porphyrin, carbon nanotube, covalently chemical functionalized, composite

Cite this article

XU, Lan-Lan, ZHAO, Hong-Bin*^,1,2, XU, Yong-Jun², WANG, Hong-Ke, LIU, Chuan-Sheng². Covalently Chemical Functionalization of Multi-walled Carbon Nanotubes with Amino Porphyrins[J]. Acta Chimica Sinica, 2008, 66(10): 1228-1234.

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氨基卟啉共价化学修饰多壁碳纳米管

Covalently Chemical Functionalization of Multi-walled Carbon Nanotubes with Amino Porphyrins

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