Electron impact(EI) mass spectra of cis,trans-4-trimethylsilylcyclohexyl alcohol analogues and their derivatives

Acta Chimica Sinica ›› 1992, Vol. 50 ›› Issue (1): 53-59. Previous Articles Next Articles

Original Articles

顺,反-4-三甲(代)甲硅烷基环己醇类似物及其衍生物的电子轰击质谱

詹东亮;朱育芬;吴俊军;张法义;唐大志;杨炜;唐士雄

中国科学院广州化学研究所

发布日期:1992-01-15

Electron impact(EI) mass spectra of cis,trans-4-trimethylsilylcyclohexyl alcohol analogues and their derivatives

ZHAN DONGLIANG;ZHU YUFEN;WU JUNJUN;ZHANG FAYI;TANG DAZHI;YANG WEI;TANG SHIXIONG

Published:1992-01-15

Abstract

The EI mass spectra of cis,trans-4-(trimethylsilyl)cyclohexyl alcohol analogs and their derivatives have been reported. The fragmentation pathways have been proposed on the basis of accurate mass measurement and metastable transition. The atomic structure of Si and steric configurations of functional groups in the stereoisomers have a distinct effect on their fragmentation behavior. The spectral patterns can be used to characterize the above stereoisomers.

Key words: SILICON, MASS SPECTROGRAPHY, STEREOCHEMISTRY, STEREOISOMERISM, CYCLOHEXANOL P, SILYL GROUP

CLC Number:

O627
O657

Cite this article

ZHAN DONGLIANG;ZHU YUFEN;WU JUNJUN;ZHANG FAYI;TANG DAZHI;YANG WEI;TANG SHIXIONG. Electron impact(EI) mass spectra of cis,trans-4-trimethylsilylcyclohexyl alcohol analogues and their derivatives[J]. Acta Chimica Sinica, 1992, 50(1): 53-59.

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顺,反-4-三甲(代)甲硅烷基环己醇类似物及其衍生物的电子轰击质谱

Electron impact(EI) mass spectra of cis,trans-4-trimethylsilylcyclohexyl alcohol analogues and their derivatives

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