DNMR study on ferrocene derivative (η-C~5H~4)~2FeTe~2S

Acta Chimica Sinica ›› 1992, Vol. 50 ›› Issue (1): 49-52. Previous Articles Next Articles

Original Articles

二茂铁衍生物(Cp)~2FeTe~2S的动态一维核磁共振谱的研究

王国雄;陈懿

南京大学化学系

发布日期:1992-01-15

DNMR study on ferrocene derivative (η-C~5H~4)~2FeTe~2S

WANG GUOXIONG;CHEN YI

Published:1992-01-15

Abstract

本文研究了桥联二茂铁衍生物(η-C~5H~4)~2FeTe~2S的动态一维核磁共振谱, 得出了桥臂反转过程的速度常数k和能垒△G^≠~2~9~1~k=56.3kJ/mol。同时用半经验分子轨道法(CNDO/2)的计算比较了两种可能过渡态的相对能垒, 指出交错型过渡态比重合型过渡态较易实现。

Key words: DYNAMICS, MECHANISM, NMR SPECTROMETRY, QUANTUM CHEMISTRY, MOLECULAR ORBITAL METHOD, REVERSE, FERROCENE P, ISOMERIZATION

CLC Number:

O641
O657

Cite this article

WANG GUOXIONG;CHEN YI. DNMR study on ferrocene derivative (η-C~5H~4)~2FeTe~2S[J]. Acta Chimica Sinica, 1992, 50(1): 49-52.

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二茂铁衍生物(Cp)~2FeTe~2S的动态一维核磁共振谱的研究

DNMR study on ferrocene derivative (η-C~5H~4)~2FeTe~2S

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