Studies on kinetics of incorporation of metal ion into porphyrin. pt. 4: Kinetic salt effect in formation reaction of Cu(II) Tβ -N-EAESPyP^4^+

Acta Chimica Sinica ›› 1993, Vol. 51 ›› Issue (3): 209-215. Next Articles

Original Articles

金属离子与卟啉的嵌入反应动力学研究 4: Cu(II)Tβ-N-EAESPyP^4^+生成反应中的动力学盐效应

陈圣云;任建国;秦子斌

武汉大学化学系

发布日期:1993-03-15

Studies on kinetics of incorporation of metal ion into porphyrin. pt. 4: Kinetic salt effect in formation reaction of Cu(II) Tβ -N-EAESPyP^4^+

CHEN SHENGYUN;REN JIANGUO;QIN ZIBIN

Published:1993-03-15

Abstract

Cu2+ reaction with I gave pH and ionic strength dependent kinetics. The equilibrium constant for association of I with ClO4- was determine spectroscopically to be 3.70 M-1 and the product had 1:1 stoichiometry. Temperature dependence of the kinetics yielded activation parameters and a mechanism involving porphyrin ring deformation is discussed.

Key words: SPECTROPHOTOMETRY, REACTION MECHANISM, REACTION KINETICS, COPPER, PERCHLORATE, INTERCALATION REACTION, PORPHYRIN, COMPLEX REACTION

CLC Number:

Cite this article

CHEN SHENGYUN;REN JIANGUO;QIN ZIBIN. Studies on kinetics of incorporation of metal ion into porphyrin. pt. 4: Kinetic salt effect in formation reaction of Cu(II) Tβ -N-EAESPyP^4^+[J]. Acta Chimica Sinica, 1993, 51(3): 209-215.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Guanglong Huang, Xiao-Song Xue. Computational Study on the Mechanism of Chen’s Reagent as Trifluoromethyl Source [J]. Acta Chimica Sinica, 2024, 82(2): 132-137.
[2]	Guoqing Cui, Yiyang Hu, Yingjie Lou, Mingxia Zhou, Yuming Li, Yajun Wang, Guiyuan Jiang, Chunming Xu. Research Progress on the Design, Preparation and Properties of Catalysts for CO₂ Hydrogenation to Alcohols [J]. Acta Chimica Sinica, 2023, 81(8): 1081-1100.
[3]	Xinpu Fu, Xiuling Wang, Weiwei Wang, Rui Si, Chunjiang Jia. Fabrication and Mechanism Study of Clustered Au/CeO₂ Catalyst for the CO Oxidation Reaction^★ [J]. Acta Chimica Sinica, 2023, 81(8): 874-883.
[4]	Zhanglong Yu, Zhongliang Li, Changjiang Yang, Qiangshuai Gu, Xinyuan Liu. Research Progress on Copper-Catalyzed Enantioselective Desymmetrization of Diols^★ [J]. Acta Chimica Sinica, 2023, 81(8): 955-966.
[5]	Minghui He, Ziqiu Ye, Guiqing Lin, Sheng Yin, Xinyi Huang, Xu Zhou, Ying Yin, Bo Gui, Cheng Wang. Research Progress of Porphyrin-Based Covalent Organic Frameworks in Photocatalysis^★ [J]. Acta Chimica Sinica, 2023, 81(7): 784-792.
[6]	Wanhong Li, Mingyue Yu, Lili Wang, Dehuang Zhu, Suhong Peng, Hui Wang, Haiyang Liu. Sovlent Influence on the Femtosecond Transient Absorption Spectra of Tetraphenylporphyrin Manganese(III) Chloride [J]. Acta Chimica Sinica, 2023, 81(4): 345-350.
[7]	Jie Yang, Lin Ling, Yuxue Li, Long Lu. Density Functional Theory Study on Thermal Decomposition Mechanisms of Ammonium Perchlorate [J]. Acta Chimica Sinica, 2023, 81(4): 328-337.
[8]	Kongxi Qiu, Jie Li, Haowen Ma, Wei Zhou, Qian Cai. Recent Advances in the Construction of Nitrogen-Containing Heterocycles via Trapping Organocopper(I) Intermediates [J]. Acta Chimica Sinica, 2023, 81(1): 42-63.
[9]	Yuguang Sui, Jinrong Zhou, Pan Liao, Wenjie Liang, Hai Xu. A Gaint Donor-Acceptor Molecular Switch Compound: Synthesis and Properties [J]. Acta Chimica Sinica, 2022, 80(8): 1061-1065.
[10]	Luocong Wang, Zhewei Li, Caiwei Yue, Peihuan Zhang, Ming Lei, Min Pu. Theoretical Study on the Isomerization Mechanism of Azobenzene Derivatives under Electric Field [J]. Acta Chimica Sinica, 2022, 80(6): 781-787.
[11]	Anni Zheng, Lei Jin, Jiaqiang Yang, Weiqing Li, Zhaoyun Wang, Fangzu Yang, Dongping Zhan, Zhongqun Tian. Advances in Pretreatments for Electroless Copper Plating on Polymer Materials [J]. Acta Chimica Sinica, 2022, 80(5): 659-667.
[12]	Qinghao Xu, Lipu Wei, Zhen Zhang, Bin Xiao. Copper Promoted Synthesis of Tetraalkylgermanes from Germanium Electrophiles and Alkyl Bromides^※ [J]. Acta Chimica Sinica, 2022, 80(4): 428-431.
[13]	Xiaoyong Fan, Shuai Zhang, Yongqiang Zhu, Maosen Jing, Kaixin Wang, Lulu Zhang, Julong Li, Lei Xu, Lei Gou, Donglin Li. Construction of Dendrite-free Lithium Metal Electrode Using Three-Dimensional Porous Copper and Zinc Coatings [J]. Acta Chimica Sinica, 2022, 80(4): 517-525.
[14]	Chaofeng Wang, Guodong Zheng, Yue Wang, Huijia Song, Xiaoyi Chen, Ruixia Gao. Preparation of Controllable Non-covalent Functionalized Carbon Nanotubes with Metalloporphyrin-Sn Network and Application to Protein Adsorption [J]. Acta Chimica Sinica, 2022, 80(2): 126-132.
[15]	Siming Yang, Airong Liu, Jing Liu, Zhaoli Liu, Weixian Zhang. Advance of Sulfidated Nanoscale Zero-Valent Iron: Synthesis, Properties and Environmental Application [J]. Acta Chimica Sinica, 2022, 80(11): 1536-1554.

金属离子与卟啉的嵌入反应动力学研究 4: Cu(II)Tβ-N-EAESPyP^4^+生成反应中的动力学盐效应

Studies on kinetics of incorporation of metal ion into porphyrin. pt. 4: Kinetic salt effect in formation reaction of Cu(II) Tβ -N-EAESPyP^4^+

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments