Acta Chimica Sinica ›› 2003, Vol. 61 ›› Issue (3): 388-392. Previous Articles     Next Articles

Original Articles

方酸作桥联配体的双核铕螯合物的电致发光

魏孝强;朱卫国;杨爱丽;李龙章;谢名贵;杨刚;林祖伦;成建波   

  1. 四川大学化学学院;湘潭大学化学化工学院;电子科技大学光电信息学院
  • 发布日期:2003-03-15

Electroluminescent Devices Based on Binuclear Europium Chelate with Square Acid as Bridge Ligand

Wei Xiaoqiang;Zhu Weiguo;Yang Aili;Li Longzhang;Xie Minggui;Yang Gang;Lin Zulun;Cheng Jianbo   

  1. Department of Chemistry,Sichuan University;Department of Chemistry, Xiangtan University;University of Electronic Science and Technology of China
  • Published:2003-03-15

A novel europium chelate, Eu_2(DBM)_4(Sq) Phen_2, which has a bridge ligand of squaric acid, was synthesized and used as organic electroluminescent materials. Five light-emitting diodes using TPD as hole-transporting material, Eu_2(DBM)_4(Sq)Phen_2 as emitting material, and A1Q as electron-transporting material were fabricated. The results indicate that this europium chelate possesses both hole-transporting and electron-transporting abilities. When the structure of device is UO/TPD, 50 nm/Eu_2(DBM)_4(Sq)Phen2, 20 nm/AlQ, 50 nm/LiF, 1 nm/Al, 200 run, the maximum luminance of 91 cd/m~2 at 16 V was achieved.

Key words: SQUARIC ACID, EUROPIUM COMPLEX, ELECTROLUMINESCENCE, LUMINESCENT MATERIALS, HYDROXY QUINOLINES, ALUMINIUM, ELECTRON TRANSFER

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