Synthesis of ferric coordination compound of bis(6-O-m-carbonyl benzenesulfonyl)-β-cyclodextrin with catalysis of oxidoreductase

Acta Chimica Sinica ›› 1995, Vol. 53 ›› Issue (6): 578-582. Previous Articles Next Articles

Original Articles

β-CD与间羧基苯磺酰氯及Fe^3^+构筑氧化还原酶

丁志刚;刘学群;詹国庆;古元冬;杨向东

中南民族学院化学系

发布日期:1995-06-15

Synthesis of ferric coordination compound of bis(6-O-m-carbonyl benzenesulfonyl)-β-cyclodextrin with catalysis of oxidoreductase

DING ZHIGANG;LIU XUEQUN;ZHAN GUOQING;GU YUANDONG;YANG XIANGDONG

Published:1995-06-15

Abstract

As β-cyclodextrin reacted with m-carbonyl benzenesulfonyl chloride in solution of pyridine at 80℃, bis(6-O-m-carbonyl benzenesulfonyl)-β-cyclodextrin, which was characterized by ^1H-^1^3C NMR, IR spectra and elemental analysis, was obtained. The ferric coordination compound of this new product could effectively catalyse benzal alcohol oxidized into benzaldehyde and benzoic acid. The catalytic rate was 4×10^4 times as much as that FeCl~3 catalysing the same reaction.

Key words: IRON, COMPLEX COMPOUNDS, OXIDOREDUCTASES, MODELS OF ENZYME

CLC Number:

O621

Cite this article

DING ZHIGANG;LIU XUEQUN;ZHAN GUOQING;GU YUANDONG;YANG XIANGDONG. Synthesis of ferric coordination compound of bis(6-O-m-carbonyl benzenesulfonyl)-β-cyclodextrin with catalysis of oxidoreductase[J]. Acta Chimica Sinica, 1995, 53(6): 578-582.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Yujie Yang, Yuxiu Gong, Tianhang Gu, Wei-xian Zhang. Progress and Environmental Research Applications of Cryo-Electron Microscopy^★ [J]. Acta Chimica Sinica, 2023, 81(8): 990-1001.
[2]	Junliang Zhou, Zhenxin Zhao, Tingyi Wu, Xiaomin Wang. Efficient Catalytic Conversion of Polysulfides in Multifunctional FeP/Carbon Cloth Interlayer for High Capacity and Stability of Lithium-sulfur Batteries [J]. Acta Chimica Sinica, 2023, 81(4): 351-358.
[3]	Xuezhi Yang, Dawei Lu, Weichao Wang, Hang Yang, Qian Liu, Guibin Jiang. Nano-Tracing: Recent Progress in Sourcing Tracing Technology of Nanoparticles^※ [J]. Acta Chimica Sinica, 2022, 80(5): 652-658.
[4]	Shangzhao Li, Zhenwu Ouyang, Junjie Zou, Dongyang Wang, Bin Xu, Liang Deng. A Mononuclear Iron Thiolate Complex with N-Heterocyclic Carbene Ligation [J]. Acta Chimica Sinica, 2022, 80(3): 272-276.
[5]	Siming Yang, Airong Liu, Jing Liu, Zhaoli Liu, Weixian Zhang. Advance of Sulfidated Nanoscale Zero-Valent Iron: Synthesis, Properties and Environmental Application [J]. Acta Chimica Sinica, 2022, 80(11): 1536-1554.
[6]	Zhuhan Zhang, Fengjing Jiang, Keke Wu, Peng Shen. Research on Iron-Lead Semi-Flow Battery Based on 3D Solid Electrode [J]. Acta Chimica Sinica, 2022, 80(1): 56-62.
[7]	Yilong Hua, Donghan Li, Tianhang Gu, Wei Wang, Ruofan Li, Jianping Yang, Wei-xian Zhang. Enrichment of Uranium from Aqueous Solutions with Nanoscale Zero-valent Iron: Surface Chemistry and Application Prospect [J]. Acta Chimica Sinica, 2021, 79(8): 1008-1022.
[8]	Zheng Cai, Yingwen Zhang, Liping Jiang, Junjie Zhu. The Construction and Application of Mn₃O₄/DOX@Lip Nano-drug Delivery System Based on Fenton-Like Reaction [J]. Acta Chimica Sinica, 2021, 79(4): 481-489.
[9]	Xue Dong, Hong Cao, Lei Xu, Zhipeng Wang, Jing Chen, Chao Xu. Advances in Environmental Coordination Chemistry of Np and Pu with Inorganic Anions in Aqueous Solution [J]. Acta Chimica Sinica, 2021, 79(12): 1415-1424.
[10]	Ziang Bai, Ruixing Chen, Hongwei Pang, Xiangxue Wang, Gang Song, Shujun Yu. Investigation on the Efficient Removal of U(VI) from Water by Sulfide Nanoscale Zero-valent Iron [J]. Acta Chimica Sinica, 2021, 79(10): 1265-1272.
[11]	Bai Yunping, Cui Chunming. Selective Hydroboration of Alkynes Enabled by a Silylene Iron(0) Dinitrogen Complex [J]. Acta Chimica Sinica, 2020, 78(8): 763-766.
[12]	Yan Tao, Liu Zhenhua, Song Xinyue, Zhang Shusheng. Construction and Development of Tumor Microenvironment Stimulus-Responsive Upconversion Photodynamic Diagnosis and Treatment System [J]. Acta Chimica Sinica, 2020, 78(7): 657-669.
[13]	Wang Xiling, Chen Jie, Ma Nana, Cong Zhiqi. Selective Hydroxylation of Alkanes Catalyzed by Cytochrome P450 Enzymes [J]. Acta Chimica Sinica, 2020, 78(6): 490-503.
[14]	Zhu Guifen, Chen Letian, Cheng Guohao, Zhao Juan, Yang Can, Zhang Yaozong, Wang Xing, Fan Jing. Efficient Removal of Levofloxacin Hydrochloride from Environment by UiO-66/CoSO₄ Composites [J]. Acta Chim. Sinica, 2019, 77(5): 434-441.
[15]	Liu Jing, Gu Tianhang, Wang Wei, Liu Ai-rong, Zhang Wei-xian. Surface Chemistry and Phase Transformation of Nanoscale Zero-Valent Iron (nZVI) in Aquatic Media [J]. Acta Chim. Sinica, 2019, 77(2): 121-129.

β-CD与间羧基苯磺酰氯及Fe^3^+构筑氧化还原酶

Synthesis of ferric coordination compound of bis(6-O-m-carbonyl benzenesulfonyl)-β-cyclodextrin with catalysis of oxidoreductase

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments