Investigation on the Efficient Removal of U(VI) from Water by Sulfide Nanoscale Zero-valent Iron

doi:10.6023/A21060263

Acta Chimica Sinica ›› 2021, Vol. 79 ›› Issue (10): 1265-1272.DOI: 10.6023/A21060263 Previous Articles Next Articles

Article

硫化纳米零价铁对水中U(VI)的高效去除研究

白子昂^a, 陈瑞兴^a, 庞宏伟^b, 王祥学^b, 宋刚^c, 于淑君^a^,^*()

a 华北电力大学环境科学与工程学院资源环境系统优化教育部重点实验室北京 102206
b 华北电力大学环境科学与工程系燃煤电站烟气多污染物协同控制实验室保定 071003
c 广州大学环境科学与工程学院广东省放射性核素污染控制与资源化重点实验室广州 510006

投稿日期:2021-06-09 发布日期:2021-07-20
通讯作者: 于淑君
基金资助:
国家自然科学基金(21906052); 国家自然科学基金(U2067215); 广东省放射性核素污染控制与资源化重点实验室开放基金(2017B030314182)

Investigation on the Efficient Removal of U(VI) from Water by Sulfide Nanoscale Zero-valent Iron

Ziang Bai^a, Ruixing Chen^a, Hongwei Pang^b, Xiangxue Wang^b, Gang Song^c, Shujun Yu^a()

a MOE Key Laboratory of Resources and Environmental Systems Optimization, College of Environmental Science and Engineering, North China Electric Power University, Beijing 102206, China
b Heibei Key Lab of Power Plant Flue Gas Multi-Pollutants Control, Department of Environmental Science and Engineering, North China Electric Power University, Baoding 071003, China
c Guangdong Provincial Key Laboratory of Radionuclides Pollution Control and Resources, School of Environmental Science and Engineering, Guangzhou University, Guangzhou 510006, China

Received:2021-06-09 Published:2021-07-20
Contact: Shujun Yu
Supported by:
National Natural Science Foundation of China(21906052); National Natural Science Foundation of China(U2067215); Research Fund Program of Guangdong Provincial Key Laboratory of Radionuclides Pollution Control and Resources(2017B030314182)

In recent years, uranium (U(VI)), a radioactive contaminant, has been widely used in industrial production and military fields. Although the industry has developed, its discharge in water poses a serious threat to the natural environment and biological health. In order to solve this problem, in this study, we prepared sulfide nano zero-valent iron (S-NZVI) material by liquid-phase reduction using NaBH₄, FeSO₄•7H₂O and Na₂S₂O₄ as main materials in N₂-filled glove box, and applied them to U(VI) removal from water. First of all, serial microscopic characterization techniques were adopted to explore the surface morphology and physicochemical properties of S-NZVI. The results showed that the S-NZVI particles are less agglomerated and more stable compared to nano zero-valent iron (NZVI). Subsequently, we investigated the effects of reaction time, temperature, pH, and background ion concentration on the removal of U(VI) by S-NZVI through macroscopic batch experiments. The consequence indicated that the maximum removal of U(VI) by S-NZVI at room temperature (20 ℃) could reach 562.5 mg•g^-1, and the reaction equilibrium could be received within 100 min. And more importantly, the eliminated process of S-NZVI is consistent with Langmuir single-molecule layer adsorption model, and the conditions for optimal performance were at ambient temperature (20 ℃) and pH=7~8. Combined with the results of macroscopic experiments and X-ray photoelectron spectroscopy (XPS) analysis, the removal mechanism of U(VI) by S-NZVI may be attributed to the synergistic effect of adsorption and redox reaction. In addition, S-NZVI can be separated from water rapidly by external magnetic field due to its magnetic property, which is convenient for material recycle and reutilization. In conclusion, this study has prepared a facile, recyclable, and efficient material for U(VI) decontamination, which may play a significant role in the future of environmental protection, nuclear waste remediation, and other related fields.

Key words: U(VI), sulfide nanoscale zero-valent iron, adsorption, redox, synergistic effect

Cite this article

Ziang Bai, Ruixing Chen, Hongwei Pang, Xiangxue Wang, Gang Song, Shujun Yu. Investigation on the Efficient Removal of U(VI) from Water by Sulfide Nanoscale Zero-valent Iron[J]. Acta Chimica Sinica, 2021, 79(10): 1265-1272.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

Fig. & Tab. 6

Figure 1. (A) SEM image of NZVI; (B) SEM image of S-NZVI; (C) TEM image of S-NZVI; (D) elemental distribution of S-NZVI; elemental distribution of (E) Fe, (F) O and (G) S; (H) content of various elements of S-NZVI

Figure 2. (A) Fitting curves of the adsorption isotherms of S-NZVI at different temperatures; (B) kinetic adsorption experiments of S-NZVI material at two concentrations of U(VI); fitted curves of (C) pseudo-first-order kinetic model and (D) pseudo-second-order kinetic model at two concentrations

温度/℃	Langmuir模型			Freundlich模型
温度/℃	K_L/(L•mg^-1)	Q_max/(mg•g^-1)	R²	K_F/(mg^1-ⁿ•Lⁿ•g^-1)	n	R²
20	0.04	562.5	0.96	90.72	1.91	0.89
25	0.14	497.9	0.98	79.98	1.93	0.92
40	0.25	173.1	0.94	50.53	2.84	0.95

Table 1. Parameters associated with the isotherm fit of the Langmuir and Freundlich adsorption models for the removal of U(VI) by S-NZVI

材料	去除量/(mg•g^-1)	参考文献
多孔石墨型氮化碳	149.7	[18]
PEI-磁性酵母复合材料	173.9	[19]
石墨负载纳米型零价铁	43.2	[20]
壳聚糖/氧化石墨烯材料	45.0	[21]
木屑季铵螯合吸附剂	99.7	[22]
改性累托石	35.5	[23]
向日葵秸秆	327.0	[24]
污泥基生物炭	80.3	[25]
羧甲基纤维素-NZVI	203.0	[26]
钙基膨润土负载NZVI	400.0	[27]
碳载零价铁	77.3	[28]
高炉水渣负载S-NZVI	99.8	[29]
硫化纳米零价铁	562.5	[本文]

Table 2. Comparison of the adsorption of S-NZVI with other materials for U(VI) removal

Figure 3. (A) Effect of pH on the adsorption of U(VI) by S-NZVI; (B) zeta potential of S-NZVI at different pH; (C) Fe 2p XPS survey spectra of S-NZVI before and after reaction with U(VI); (D) comparison of iron dissolution from S-NZVI and NZVI in water and U(VI)

Figure 4. Hysteresis lines (A) before and (B) after the reaction of S-NZVI and NZVI; (C) effect of different concentrations of NaNO3 on the adsorption of U(VI) by S-NZVI; (D) effect of various anions and cations on the adsorption of U(VI) by S-NZVI

References 45

[1]	Shi, W. Q.; Yuan, L. Y.; Li, Z. J.; Lan, J. H.; Zhao, Y. L.; Chai, Z. F. Radiochim. Acta 2012, 100, 727. doi: 10.1524/ract.2012.1961
[2]	Pritee, P.; Madhurima, P.; Piyush, K. P. J. J. Nucl. Mater. 2021, 328, 89.
[3]	Shao, Y.; Yang, G. S.; Zhang, J. L.; Luo, M.; Ma, L. L.; Xu, D. D. Acta Chim. Sinica 2021, 79, 716. (in Chinese) doi: 10.6023/A21020074
	邵阳, 杨国胜, 张继龙, 罗敏, 马玲玲, 徐殿斗, 化学学报, 2021, 79, 716.) doi: 10.6023/A21020074
[4]	Li, Z. N.; Sha, H. Y.; Yang, N.; Yuan, Y.; Zhu, G. S. Acta Chim. Sinica 2019, 77, 469. (in Chinese) doi: 10.6023/A19010028
	(李樟楠, 沙浩岩, 杨南, 元野, 朱广山, 化学学报, 2019, 77, 469.) doi: 10.6023/A19010028
[5]	Pang, H. W.; Tang, H.; Wang, J. Q.; Wang, X. X.; Yu, S. J. Inorg. Mater. 2020, 35, 381.
[6]	Wang, N.; Pang, H. W.; Yu, S. J.; Gu, P. C.; Song, S.; Wang, H. Q.; Wang, X. K. Acta Chim. Sinica 2019, 77, 143. (in Chinese) doi: 10.6023/A18090404
	(王宁, 庞宏伟, 于淑君, 顾鹏程, 宋爽, 王宏青, 王祥科, 化学学报, 2019, 77, 143.) doi: 10.6023/A18090404
[7]	Wang, X. D.; Liu, S. J.; Xu, M. Environ. Chem. 2020, 40, 1. (in Chinese)
	(王煦栋, 刘思金, 徐明, 环境化学, 2020, 40, 1.)
[8]	Liu, X. L.; Pang, H. W.; Liu, X. W.; Li, Q.; Zhang, N.; Mao, L.; Qiu, M. Q.; Hu, B. W.; Yang, H.; Wang, X. K. The Innovation 2021, 2, 100076. doi: 10.1016/j.xinn.2021.100076
[9]	Chen, H. J.; Huang, S. Y.; Zhang, Z. B.; Liu, Y. H.; Wang, X. K. Acta Chim. Sinica 2017, 75, 560. (in Chinese) doi: 10.6023/A17010039
	(陈海军, 黄舒怡, 张志宾, 刘云海, 王祥科, 化学学报, 2017, 75, 560.) doi: 10.6023/A17010039
[10]	Tang, J.; Feng, H. P.; Dong, H. R.; Zhang, Y.; Liu, S. S.; Zeng, G. M. Acta Chim. Sinica 2017, 75, 575. (in Chinese) doi: 10.6023/A17020045
	(汤晶, 冯浩朋, 董浩然, 章毅, 刘诗思, 曾光明, 化学学报, 2017, 75, 575.) doi: 10.6023/A17020045
[11]	Li, Z. X.; Han, Y. T.; Xu, Y. Q.; Yang, Y.; Chen, J. W. Rock. Min. Anal. 2016, 35, 634. (in Chinese)
	(李志雄, 韩奕彤, 徐永强, 杨洋, 陈家玮, 岩矿测试, 2016, 35, 634.)
[12]	Yu, S. J.; Wang, X. X.; Liu, Y. F.; Chen, Z. S.; Wu, Y. H.; Liu, Y.; Pang, H. W.; Song, G.; Chen, J. R.; Wang, X. K. Chem. Eng. J. 2019. 365, 51. doi: 10.1016/j.cej.2019.02.024
[13]	Huang, K. Y.; Shen, Y. J.; Wang, X. Y.; Wang, X. R.; Yuan, W. Y.; Zhang, C. L.; Bai, J. F.; Wang, J. W. Environ. Eng. 2020, 38, 203. (in Chinese)
	(黄开友, 申英杰, 王晓岩, 王兴润, 苑文仪, 张承龙, 白建峰, 王景伟, 环境工程, 2020, 38, 203.)
[14]	Pang, H. W.; Wu, Y. H.; Huang, S. Y.; Ding, C. C.; Li, S.; Wang, X. X.; Yu, S. J.; Chen, Z. S.; Song, G.; Wang, X. K. Inorg. Chem. Front. 2018, 5, 2657. doi: 10.1039/C8QI00779A
[15]	Na, L. Y.; Zhang, L. Y.; Zhang, F. J.; Hua, R. N. Mater. Rep. 2020, 34, 22030. (in Chinese)
	(那立艳, 张丽影, 张凤杰, 华瑞年, 材料导报, 2020, 34, 22030.)
[16]	Zhao, Z. G.; Tang, X. Y. J. Henan Polytechnic University Nat. Sci. 2002, 21, 1. (in Chinese)
	(赵志根, 唐修义, 焦作工学院学报(自然科学版), 2002, 21, 1.)
[17]	Liu, Y.; Huo, Y. Z.; Wang, X. X.; Yu, S. J.; Ai, Y. J.; Chen, Z. S.; Zhang, P.; Chen, L.; Song, G.; Alharbi, N. S.; Rabah, S. O.; Wang, X. K. J. Clean. Prod. 2021, 278, 123216. doi: 10.1016/j.jclepro.2020.123216
[18]	Zhang, C. L.; Liu, Y.; Li, X.; Chen, H. X.; Wen, T.; Jiang, Z. H; Ai, Y. J.; Yu, S. J.; Sun, Y. B.; Tasawar, H.; Wang, X. K. Chem. Eng. J. 2018, 346, 406. doi: 10.1016/j.cej.2018.03.186
[19]	Wu, S. Y.; Li, S. Y.; Hu, J. Y.; He, J. Q.; Wang, G. H.; Rong, L. S.; Jin, Y. Y. Acta Materiae Compositae Sinica 2020, 37, 11. (in Chinese)
	(伍随意, 李仕友, 胡俊毅, 贺俊钦, 王国华, 荣丽杉, 金远远, 复合材料学报, 2020, 37, 11.)
[20]	Liu, X.; Li, X. Y.; Chen, Y. J.; Sang, W. X.; Chen, R. Chin. J. Nonferrous Met. 2020, 30, 1967. (in Chinese)
	(刘学, 李小燕, 陈玉洁, 桑伟璇, 陈蓉, 中国有色金属学报, 2020, 30, 1967.)
[21]	Li, S. Y.; Shi, D. F.; Tang, Z. P.; Xie, S. B.; Liu, Y. J.; Ling, H. Acta Scientiae Circumstantiae 2017, 37, 1388. (in Chinese)
	(李仕友, 史冬峰, 唐振平, 谢水波, 刘迎九, 凌辉, 环境科学学报, 2017, 37, 1388.)
[22]	Deng, W. J.; Zhou, S. K.; Liu, Y. J.; Zeng, G. M.; Jiang, H. H.; Kang, L.; Fang, L. Chin. J. Nonferrous Met. 2015, 25, 2604. (in Chinese)
	(邓文静, 周书葵, 刘迎九, 曾光明, 江海浩, 康丽, 方良, 中国有色金属学报, 2015, 25, 2604.)
[23]	Guo, Y. D.; Liang, P.; Li, X. M.; Liu, M. Q. China Ceramics 2014, 50, 24. (in Chinese)
	(郭亚丹, 梁平, 李效萌, 刘明清, 中国陶瓷, 2014, 50, 24.)
[24]	Ai, L.; Luo, X. G.; Lin, X. Y.; Mei, Q. Chem. Ind. Forest Prod. 2014, 34, 9. (in Chinese)
	(艾莲, 罗学刚, 林晓艳, 梅强, 林产化学与工业, 2014, 34, 9.)
[25]	Mo, G. H.; Nong, H. D.; Hu, Q.; Xie, S. B.; Liu, H. J.; Zeng, T. T. Fine Chemicals 2021, 38, 395. (in Chinese)
	(莫官海, 农海杜, 胡青, 谢水波, 刘红娟, 曾涛涛, 精细化工, 2021, 38, 395.)
[26]	I-Carmen, P.; Petru, F.; Doina, H.; Ionel, H.; Thomas, B. C.; Richard, A. C.. J. Nucl. Mater. 2013, 443, 250. doi: 10.1016/j.jnucmat.2013.07.018
[27]	Xiong, X. H.; Chen, Q. S.; Zhou, J. W.; Liu, X. Y.; Wang, L. Y.; Huang, B.; Zhu, Y. A.; Luo, T. A. Non-metallic Minerals 2018, 41, 83. (in Chinese)
	(熊小红, 陈泉水, 周佳玮, 刘星雨, 王玲钰, 黄彬, 朱业安, 罗太安, 非金属矿, 2018, 41, 83.)
[28]	Wang, J. Q.; Pang, H. W.; Tang, H.; Yu, S. J.; Zhu, H. T.; Wang, X. X. J. Inorg. Mater. 2020, 35, 373. (in Chinese)
	(王佳琦, 庞宏伟, 唐昊, 于淑君, 朱洪涛, 王祥学, 无机材料学报, 2020, 35, 373.)
[29]	Sun, Q. N.; Zhang, R. B.; Deng, M. J.; Li, Y.; Wang, X. J. Environ. Sci. 2021, 42, 867. (in Chinese)
	(孙秋楠, 张荣斌, 邓曼君, 李远, 王学江, 环境科学, 2021, 42, 867.)
[30]	Liu, Q. W.; Ding, Y. D.; Liao, Q.; Wang, H.; Zhu, X.; Zeng, F. Q. Chin. Sci. Bull. 2019, 64, 2441. (in Chinese) doi: 10.1360/N972019-00061
	(刘骐玮, 丁玉栋, 廖强, 王宏, 朱恂, 曾烽棋, 科学通报, 2019, 64, 2441.)
[31]	Liu, Y.; Pang, H. W.; Wang, X. X.; Yu, S. J.; Chen, Z. S.; Zhang, P.; Chen, L.; Song, G.; Alharbi, N. S.; Rabah, S. O.; Wang, X. K. Chem. Eng. J. 2021, 406, 127139. doi: 10.1016/j.cej.2020.127139
[32]	Guo, W. J.; Liang, X. F.; Lin, D. S.; Xu, Y. M.; Wang, L.; Sun, Y. B.; Qin, X. Environ. Sci. 2013, 34, 3716. (in Chinese)
	(郭文娟, 梁学峰, 林大松, 徐应明, 王林, 孙约兵, 秦旭, 环境科学, 2013, 34, 3716.)
[33]	Ayben, K. Appl. Radiat. Isot. 2003, 58, 713. doi: 10.1016/S0969-8043(03)00116-7
[34]	Tan, P. L. J. Catal. 2016, 338, 21. doi: 10.1016/j.jcat.2016.01.027
[35]	Toru, Y.; Peter, H. Appl. Surf. Sci. 2008, 254, 2441. doi: 10.1016/j.apsusc.2007.09.063
[36]	Chen, R.; Sang, W. X.; Li, X. Y.; He, D. W.; Wang, Y.; Cao, X. G. Industrial Water Treatment 2021, 41, 66. (in Chinese)
	(陈蓉, 桑伟璇, 李小燕, 何登武, 王杨, 曹小岗, 工业水处理, 2021, 41, 66.)
[37]	Fan, J.; Hu, Y. B.; Li, X. Y. ACS Sustain. Chem. Eng. 2018, 6, 15135. doi: 10.1021/acssuschemeng.8b03593
[38]	Sourjay, B.; Subhasis, G. Environ. Sci. Technol. 2018, 52, 11078. doi: 10.1021/acs.est.8b02399
[39]	Sheng, G. D.; Ahmed, A.; Wafa, S.; Shatha, M.; Sheng, J.; Wang, X. K.; Li, H.; Huang, Y. Y. Carbon 2016, 99, 123. doi: 10.1016/j.carbon.2015.12.013
[40]	Huang, H.; Wei, Y. W.; Wang, W. Y.; Liu, M. M.; Niu, Z. R. Acta Scientiae Circumstantiae 2020, 40, 128. (in Chinese)
	(黄华, 魏雨薇, 王婉悦, 刘淼淼, 牛志睿, 环境科学学报, 2020, 40, 128.)
[41]	Li, X. Y.; Zhang, M.; Liu, Y. B.; Li, X.; Yang, B.; Hua, R.; Liu, Y. H. Chin. J. Nonferrous Met. 2015, 25, 3505. (in Chinese) doi: 10.1016/S1003-6326(15)63992-9
	(李小燕, 张明, 刘义保, 李寻, 杨波, 花榕, 刘云海, 中国有色金属学报, 2015, 25, 3505.)
[42]	Yan, S.; Hua, B.; Bao, Z. Y.; Yang, J.; Liu, C. X.; Deng, B. L. Environ. Sci. Technol. Lett. 2010, 44, 7783. doi: 10.1021/es9036308
[43]	Gao, S. M.; Wang, X. D.; Qin, L.; Luo, S.; Zhao, X.; Liu, S. S.; Wang, L. S. J. Nanjing Univ. (Nat. Sci.) 2007, 358. (in Chinese)
	(高树梅, 王晓栋, 秦良, 罗斯, 赵欣, 刘树深, 王连生, 南京大学学报(自然科学版), 2007, 358.)
[44]	Pang, H. W.; Diao, Z. F.; Wang, X. X.; Ma, Y.; Yu, S. J.; Zhu, H. T.; Chen, Z. S.; Hu, B. W.; Chen, J. R.; Wang, X. K. Chem. Eng. J. 2019, 366, 368. doi: 10.1016/j.cej.2019.02.098
[45]	Liang, W. Y. M.S. Thesis, Hunan University, Changsha, 2019. (in Chinese)
	(梁玮瑜, 硕士论文, 湖南大学,长沙, 2019.)

硫化纳米零价铁对水中U(VI)的高效去除研究

Investigation on the Efficient Removal of U(VI) from Water by Sulfide Nanoscale Zero-valent Iron

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Fig. & Tab. 6

References 45

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Hangqing Lin, Ruoru Ma, Yilan Jiang, Murong Xu, Yangpeng Lin, Kezhao Du. Research Progress of Materials Used for Elemental Halogen Capture [J]. Acta Chimica Sinica, 2024, 82(1): 62-74.
[2]	Yuchun Han, Yilin Wang. Retrospect and Prospect of Long-lasting Antibacterial Materials^★ [J]. Acta Chimica Sinica, 2023, 81(9): 1196-1201.
[3]	Shaojuan Zeng, Xueqi Sun, Yinge Bai, Lu Bai, Shuang Zheng, Xiangping Zhang, Suojiang Zhang. Research Progress of CO₂ Capture and Separation by Functionalized Ionic Liquids and Materials^★ [J]. Acta Chimica Sinica, 2023, 81(6): 627-645.
[4]	Fengbin Zheng, Kun Wang, Tian Lin, Yinglong Wang, Guodong Li, Zhiyong Tang. Research Progress on the Preparation of Metal-Organic Frameworks Encapsulated Metal Nanoparticle Composites and Their Catalytic Applications^★ [J]. Acta Chimica Sinica, 2023, 81(6): 669-680.
[5]	Ziqi Li, Liwei Liu, Chenghui Mao, Changkai Zhou, Minqi Xia, Zhen Shen, Yue Guo, Qiang Wu, Xizhang Wang, Lijun Yang, Zheng Hu. Cobalt-Substituted Polyoxometalates as Soluble Mediators to Boost the Lithium-Sulfur Battery Performance [J]. Acta Chimica Sinica, 2023, 81(6): 620-626.
[6]	Kaiqing Wang, Shuo Yuan, Wangdong Xu, Dan Huo, Qiulin Yang, Qingxi Hou, Dehai Yu. Preparation and Adsorption Properties of ZIF-8@B-CNF Composite Aerogel [J]. Acta Chimica Sinica, 2023, 81(6): 604-612.
[7]	Zhao Zhenxin, Yao Yikun, Chen Jiajun, Niu Rong, Wang Xiaomin. A High-entropy Phosphate Cathode Host towards High-stability Lithium-sulfur Batteries [J]. Acta Chimica Sinica, 2023, 81(5): 496-501.
[8]	Jiangmin Jiang, Xinran Zheng, Yating Meng, Wenjie He, Yaxin Chen, Quanchao Zhuang, Jiaren Yuan, Zhicheng Ju, Xiaogang Zhang. Research on the Preparation and Potassium Storage Performance of F, N Co-doped Porous Carbon Nanosheets [J]. Acta Chimica Sinica, 2023, 81(4): 319-327.
[9]	Wentao Wang, Xinting Lai, Shiquan Yan, Lei Zhu, Yuyuan Yao, Liming Ding. Synergistic Treatment of Dye Wastewater by the Adsorption-Degradation of a Bifunctional Aerogel [J]. Acta Chimica Sinica, 2023, 81(3): 222-230.
[10]	Bing Zheng, Zhe Wang, Jing He, Jiao Zhang, Wenbo Qi, Mengyuan Zhang, Haitao Yu. Structure and Work Function of Alkaline (Earth) Metal-Bilayer α-Borophene Nanocomposite: A Theoretical Study [J]. Acta Chimica Sinica, 2023, 81(10): 1357-1370.
[11]	Zhaowei Tian, Weimin Da, Lei Wang, Yusen Yang, Min Wei. Structural Design and Research Progress of Heterogeneous Catalysts for the Preparation of Second Generation Biodiesel [J]. Acta Chimica Sinica, 2022, 80(9): 1322-1337.
[12]	Zhenhua Wang, Cong Ma, Ping Fang, Haichao Xu, Tiansheng Mei. Advances in Organic Electrochemical Synthesis [J]. Acta Chimica Sinica, 2022, 80(8): 1115-1134.
[13]	Fang Liu, Tingting Pan, Xiurong Ren, Weiren Bao, Jiancheng Wang, Jiangliang Hu. Research on Preparation and Benzene Adsorption Performance of HCDs@MIL-100(Fe) Adsorbents [J]. Acta Chimica Sinica, 2022, 80(7): 879-887.
[14]	Tiantian Lü, Wen Ma, Dongsun Zhan, Yanmin Zou, Jilong Li, Meiling Feng, Xiaoying Huang. Two New Three-Dimensional Lanthanide Metal-organic Frameworks for the Highly Efficient Removal of Cs⁺ Ions^※ [J]. Acta Chimica Sinica, 2022, 80(5): 640-646.
[15]	Yaru Wei, Jing Ma, Tingting Yuan, Jiawei Jiang, Yinli Duan, Juanqin Xue. Preparation and Adsorption Properties of Lithium Chloride Intercalation Carbon Nitride [J]. Acta Chimica Sinica, 2022, 80(4): 494-502.