Reaction of dimethylsilyene with compounds containing allylmethyl ether moieties

Acta Chimica Sinica ›› 1990, Vol. 48 ›› Issue (5): 516-520. Previous Articles

Original Articles

二甲基硅烯与含烯丙基甲醚结构的化合物的反应

王东;陈德恒

加拿大麦吉尔大学化学系

发布日期:1990-05-15

Reaction of dimethylsilyene with compounds containing allylmethyl ether moieties

WANG DONG;CHEN DEHENG

Published:1990-05-15

Abstract

The reaction of dimethylsilylene with the compounds containing allylmethyl ether moieties gave allyldimethylmethoxysiloxane with very good chemo- and regioselectivities. Thus, siloxane I was obtained in 80% yield from ether II and dimethylsilene. The rearrangement of allylic double bond took placed in the course of these reactions.

Key words: SELECTIVITY, REARRANGEMENT REACTION, METHYL ETHER, ALLYL GROUP, PINENE, SILYLENE, ELECTROPHILIC REACTION, OCTADINOL P, DODECENE P

CLC Number:

O621

Cite this article

WANG DONG;CHEN DEHENG. Reaction of dimethylsilyene with compounds containing allylmethyl ether moieties[J]. Acta Chimica Sinica, 1990, 48(5): 516-520.

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二甲基硅烯与含烯丙基甲醚结构的化合物的反应

Reaction of dimethylsilyene with compounds containing allylmethyl ether moieties

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