Study of biomimetic oxidation catalyzed by the model compound of cytochrome P-450:III. The mechanistic studies of the oxygenation of cyclohexane catalyzed by TPPFe(III)Cl or/and TPPMn (III) Cl

Acta Chimica Sinica ›› 1989, Vol. 47 ›› Issue (11): 1135-1138. Previous Articles

Original Articles

模拟细胞色素P-450和仿生氧化反应研究III. 有关用TPPFe(III)Cl及TPPMn(III)Cl催化的环己烷充氧化反应机理的初步探讨

朱申杰;张春豪;白令君

南开大学化学系

发布日期:1989-11-15

Study of biomimetic oxidation catalyzed by the model compound of cytochrome P-450:III. The mechanistic studies of the oxygenation of cyclohexane catalyzed by TPPFe(III)Cl or/and TPPMn (III) Cl

ZHU SHENJIE;ZHANG CHUNHAO;BAI LINGJUN

Published:1989-11-15

Abstract

The reaction systems for oxygenation of cyclohexane with ArIO catalyzed by TPPFe(III)Cl or/and TPPMn(III)Cl were studied by UV-vis. and ESR spectroscopies.. From the spectroscopic data, the intermediate in the TPPFe(III)Cl-catalyzed system may be TPPFe(V)(O)Cl or TPPFe(IV)(Cl)O? and the intermediate in the TPPMn(III)Cl-catalyzed system may be [ArI(Cl)OMn(IV)TPP]2O. Based on this result, 2 different possible mechanisms for these 2 catalytic oxygenation reactions of cyclohexane were proposed.

Key words: CATALYSIS, OXIDATION, REACTION MECHANISM, BENZENE P, IRON COMPLEX, ORGANOIODINE COMPOUNDS, SPECTROGRAPHIC ANALYSIS, CYTOCHROME, BIONICS, CYCLOHEXANE

CLC Number:

O643

Cite this article

ZHU SHENJIE;ZHANG CHUNHAO;BAI LINGJUN. Study of biomimetic oxidation catalyzed by the model compound of cytochrome P-450:III. The mechanistic studies of the oxygenation of cyclohexane catalyzed by TPPFe(III)Cl or/and TPPMn (III) Cl[J]. Acta Chimica Sinica, 1989, 47(11): 1135-1138.

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模拟细胞色素P-450和仿生氧化反应研究III. 有关用TPPFe(III)Cl及TPPMn(III)Cl催化的环己烷充氧化反应机理的初步探讨

Study of biomimetic oxidation catalyzed by the model compound of cytochrome P-450:III. The mechanistic studies of the oxygenation of cyclohexane catalyzed by TPPFe(III)Cl or/and TPPMn (III) Cl

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