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Acta Chimica Sinica ›› 2005, Vol. 63 ›› Issue (20): 1866-1870. Previous Articles     Next Articles

Original Articles

2-(2,5-二羟基苯基)-5-甲基-2,5-二氢吡咯并[3,4]富勒烯的合成和电子光谱的理论研究

尹起范1,2，朱玉兰*,1,2，曹 丽1，阚玉和a,c, 周建峰1，南京熙2，苏忠民3   

  1. (1淮阴师范学院化学系 江苏省低维材料化学重点建设实验室 淮安 223300)
    (2延边大学理工学院化学系 延吉 133002)
    (3东北师范大学化学学院功能材料化学研究所 长春 130024)
  • 投稿日期:2005-12-01 修回日期:2005-06-17 发布日期:2010-12-10
  • 通讯作者: 朱玉兰

Synthesis of [2-(2,5-Dihydroxyphenyl)-5-methyl-2,5-dihydropyrrolino]- [3,4]fullerene and Theoretical Studies on Its Electronic Spectra

YIN Qi-Fan1,2, ZHU Yu-Lan*,1,2, CAO Li1, KAN Yu-He1,3, ZHOU Jian-Feng1, NAN Jing-Xi2, SU Zhong-Min3   

  1. (1 Department of Chemistry, Huaiyin Teachers’ College, Jiangsu Key Laboratory for Chemistry of
    Low-dimensional Materials, Huai′an 223300)
    (2 Department of Chemistry, Science and Engineering College, Yanbian University, Yanji 133002)
    (3 Institute of Functional Material Chemistry, Northeast Normal University, Changchun 130024)
  • Received:2005-12-01 Revised:2005-06-17 Published:2010-12-10
  • Contact: ZHU Yu-Lan

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A new compound [2-(2,5-dihydroxyphenyl)-5-methyl-2,5-dihydropyrrolino][3,4]fullerene was synthesized by the 1,3-dipolar cycloaddition reaction between the fullerene (C60) and azomethine ylide (prepared from 2-aminopropanoic acid and 2,5-dihydroxybenzal), which was characterized by 1H NMR, FT-IR, UV-vis spectra and elemental analysis. Its properties of electrochemistry and fluorescence were also studied. The geometry configurations of the compound were optimized using the density functional theory at B3LYP/6-31G level. The electronic spectra of the compound were studied by INDO/S method. The computational result (434.2 nm) accorded with the experimental one (432.0 nm).

Key words: C60-pyrrolidine derivative, cyclic voltammetry, electronic spectra, density functional theory