A molecular beam study of the reactions of fluorine atoms with CH3F and CH3Cl

Acta Chimica Sinica ›› 1988, Vol. 46 ›› Issue (1): 82-84. Previous Articles Next Articles

Original Articles

用分子束研究.F(^2P)与CH3F和CH3Cl的化学反应

史济良;李方琳;蒋锡夔;邱元武;周士康;刘颂豪

中国科学院上海有机化学研究所;中国科学院安徽光学精密机械研究所

发布日期:1988-01-15

A molecular beam study of the reactions of fluorine atoms with CH3F and CH3Cl

SHI JILIANG;LI FANGLIN;JIANG XIKUI;QIU YUANWU;ZHOU SHIKANG;LIU SONGHAO

Published:1988-01-15

Abstract

The reactions of fluorine atoms with CH3F and CH3Cl have been investigated by mol. beam set-up and laser spectroscopy. In these systems, in addition to the hydrogen abstraction reactions, radical coupling reactions also occur. Furthermore, the chemiluminescence of HF has also been observed in these reactions. These results are valuable for the discussion of laser induced chem. reaction mechanism.

Key words: METHANE P, REACTION MECHANISM, FLUORINE, CHLOROHYDROCARBON, CARBENE, FREE RADICAL, QUENCHING EFFECTS, FLUOROHYDROCARBON, FREE RADICAL REACTION, LASER SPECTROMETRY

CLC Number:

O621.16

Cite this article

SHI JILIANG;LI FANGLIN;JIANG XIKUI;QIU YUANWU;ZHOU SHIKANG;LIU SONGHAO. A molecular beam study of the reactions of fluorine atoms with CH3F and CH3Cl[J]. Acta Chimica Sinica, 1988, 46(1): 82-84.

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用分子束研究.F(^2P)与CH3F和CH3Cl的化学反应

A molecular beam study of the reactions of fluorine atoms with CH3F and CH3Cl

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