Research on polymer-supported rare earth metal complexes IV. synthesis characterization and catalytic activity of rare-earth metal complexes supported on polymer containing sulfinyl groups

Acta Chimica Sinica ›› 1987, Vol. 45 ›› Issue (8): 801-804. Previous Articles Next Articles

Original Articles

聚合物载体-稀土金属配合物的研究IV.含亚硫酰基聚合物载体-稀土金属配合物的合成,表征及其催化活性

李玉良;潘鹤枫;李广全;欧阳均

中国科学院长春应用化学研究所

发布日期:1987-08-15

Research on polymer-supported rare earth metal complexes IV. synthesis characterization and catalytic activity of rare-earth metal complexes supported on polymer containing sulfinyl groups

LI YULIANG;PAN HEFENG;LI GUANGQUAN;OU YANGJUN

Published:1987-08-15

Abstract

Styrene-2-(methylsulfinyl)ethyl methacrylate copolymer-supported MCl3 complexes, where M = La, Pr, Nd, Eu, Ho, Er, Tm, and Yb, were prepared and characterized by IR spectroscopy. The catalytic activity of the polymer-supported NdCl3-(iso-Bu)3Al system towards stereospecific polymerisation of butadiene was 2-3 times higher than that of NdCl3-(iso-Bu)3Al-DMSO system. The cis-1,4 content of polybutadiene formed was >98%.

Key words: INFRARED SPECTROPHOTOMETRY, CATALYST, STYRENE, POLYMER CHARACTERIZATION, COPOLYMERS, CARRIERS, RARE EARTH METAL COMPLEX, SULFENYL COMPOUNDS, PROPERTIES, METHYLPROPENOIC ACID ESTER P

CLC Number:

O631.3
O643

Cite this article

LI YULIANG;PAN HEFENG;LI GUANGQUAN;OU YANGJUN. Research on polymer-supported rare earth metal complexes IV. synthesis characterization and catalytic activity of rare-earth metal complexes supported on polymer containing sulfinyl groups[J]. Acta Chimica Sinica, 1987, 45(8): 801-804.

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聚合物载体-稀土金属配合物的研究IV.含亚硫酰基聚合物载体-稀土金属配合物的合成,表征及其催化活性

Research on polymer-supported rare earth metal complexes IV. synthesis characterization and catalytic activity of rare-earth metal complexes supported on polymer containing sulfinyl groups

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