Cooperative Binding of Dyes by Biquinolino Modified β-cyclodextrin Dimers

Abstract

The complex stability constants for the 1∶1 inclusion complexation of 2,2'-biquinoline-4,4'- dicarboxy-bridged bis(

-cyclodextrin)s with dye guests have been determined by means of fluorescent titration at 25 ℃ in phosphate buffer solution (pH 7.2). Possessing more rigid and bigger

-electron systems of tethers, biquinolino-modified

-cyclodextrin dimers can form more stable complexes with not only the T-shaped RhB but also the linear guest AR than the corresponding bipyridino-tethered bis(

-cyclodextrin)s. 2D NMR investigations for the complexation between host and guest validated the cooperative binding of bis(

-cyclodextrin)s with dye guests. The inclusion complexation behaviors of bis(

-cyclodextrin)s with dyes were discussed from the viewpoints of size/shape-fitting relationship between host and guest as well as the cooperative contribution of several weak forces.

Key words: bridged bis(β-cyclodextrin), fluorescence titration, molecular recognition, dye, supramolecular chemistry

Cite this article

SONG Yun,LIU Yu*. Cooperative Binding of Dyes by Biquinolino Modified β-cyclodextrin Dimers[J]. Acta Chimica Sinica, 2005, 63(2): 103-108.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Wentao Wang, Xinting Lai, Shiquan Yan, Lei Zhu, Yuyuan Yao, Liming Ding. Synergistic Treatment of Dye Wastewater by the Adsorption-Degradation of a Bifunctional Aerogel [J]. Acta Chimica Sinica, 2023, 81(3): 222-230.
[2]	Yinghong Yan, Pingzhao Liang, Yang Zou, Lin Yuan, Xiaojun Peng, Jiangli Fan, Xiaobing Zhang. Structure and Properties Regulation of Organic Photosensitizers and Application in Photodiagnosis and Treatment^★ [J]. Acta Chimica Sinica, 2023, 81(11): 1642-1662.
[3]	Ruomei Liu, Yanhui Feng, Zhuo Li, Shan Lu, Tianyong Guan, Xingjun Li, Yan Liu, Zhuo Chen, Xueyuan Chen. A Novel Near-infrared Responsive Lanthanide Upconversion Nanoplatform for Drug Delivery Based on Photocleavage of Cypate^※ [J]. Acta Chimica Sinica, 2022, 80(4): 423-427.
[4]	Ning Xu, Qinglong Qiao, Xiaogang Liu, Zhaochao Xu. Enhancing Brightness and Photostability of Organic Small Molecular Fluorescent Dyes Through Inhibiting Twisted Intramolecular Charge Transfer (TICT)^※ [J]. Acta Chimica Sinica, 2022, 80(4): 553-562.
[5]	Zitao Wang, Yaozu Liu, Yujie Wang, Qianrong Fang. A New Covalent Organic Framework Modified with Sulfonic Acid for CO₂ Uptake and Selective Dye Adsorption [J]. Acta Chimica Sinica, 2022, 80(1): 37-43.
[6]	Jing Fang, Wenjuan Zhao, Minghao Zhang, Qianrong Fang. A Novel Amide-functionalized Covalent Organic Framework for Selective Dye Adsorption [J]. Acta Chimica Sinica, 2021, 79(2): 186-191.
[7]	Ling-Yan Li, Wei Zheng, Cheng-Hui Li. A Facile Synthetic Method and New Derivatives of Phthalorubines [J]. Acta Chimica Sinica, 2021, 79(1): 81-86.
[8]	Zhu Congtan, Yang Ying, Zhao Beikai, Lin Feiyu, Luo Yuan, Ma Shupeng, Zhu Liu, Guo Xueyi. Electrochemical Synthesis of PEDOT and Its Application in Solid-State Dye-sensitized Solar Cells [J]. Acta Chimica Sinica, 2020, 78(10): 1102-1110.
[9]	Yang Ying, Chen Tian, Pan Dequn, Zhang Zheng, Guo Xueyi. Research Progress of Bifacial Solar Cells with Transparent Counter Electrode [J]. Acta Chim. Sinica, 2018, 76(9): 681-690.
[10]	Pan Bina, Zhu Yi-Zhou, Qiu Changjuana, Wang Binga, Zheng Jian-Yu. Synthesis of Phenothiazine Dyes Featuring Benzothiadiazole Unit for Efficient Dye-sensitized Solar Cells [J]. Acta Chim. Sinica, 2018, 76(3): 215-223.
[11]	Zhao Cong, Ma Ying, Wang Yang, Zhou Xue, Li Huizeng, Li Mingzhu, Song Yanlin. Research Progress of Photonic Crystal Solar Cells [J]. Acta Chimica Sinica, 2018, 76(1): 9-21.
[12]	Qin Tianyi, Zeng Yi, Chen Jinping, Yu Tianjun, Li Yi. Progress in Organic Fluorescent Thermometers [J]. Acta Chim. Sinica, 2017, 75(12): 1164-1172.
[13]	Chen Meihua, Pan Zheng, Yin Yuefeng, Liu Jie, Liu Mengyuan, Jia Zijun, Liang Guijie. Panchromatic and High-efficient Energy Transfer Assembly Based on Type I Core-shell Quantum Dots [J]. Acta Chim. Sinica, 2016, 74(4): 330-334.
[14]	Zhang Xiaoyu, Ying Weijiang, Wu Wenjun, Li Jing, Hua Jianli. Synthesis and Photovoltaic Performance of (Octyloxyphenyl)pyrido-[3,4-b]pyrazine-based Sensitizers for Dye-sensitized Solar Cells [J]. Acta Chim. Sinica, 2015, 73(3): 272-280.
[15]	Ma Yingzhuang, Zheng Lingling, Zhang Lipei, Chen Zhijian, Wang Shufeng, Qu Bo, Xiao Lixin, Gong Qihuang. A Novel Organic Disulfide/Thiolate Redox Mediator for Iodine-free Dye-sensitized Solar Cells [J]. Acta Chim. Sinica, 2015, 73(3): 257-260.

联喹啉桥联双环糊精对染料客体分子的协同键合