Simple and Rapid Synthesis of Fe(PO3)3 with Three-dimensional Networks Morphology by a Novel Thermal Decomposition of Iron Phosphonate

doi:10.6023/A1112312

Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (12): 1412-1416.DOI: 10.6023/A1112312 Previous Articles

Note

有机膦酸配合物热分解法制备三维网状形貌的偏磷酸铁

陈炼^a, 章莺鸿^b, 周益明^a, 谢孔微^a, 陈煜^a, 唐亚文^a, 陆天虹^a

a 江苏省新型动力电池重点实验室南京师范大学化学与材料科学学院南京 210046;
b 南京工程高等职业学校地质工程系南京 211135

投稿日期:2011-12-31 修回日期:2012-04-25 发布日期:2012-04-20
通讯作者: 周益明 E-mail:zhouyiming@njnu.edu.cn
基金资助:
国家自然科学基金(Nos. 21005039, 21073094)和江苏高校优势学科建设工程资助项目

Simple and Rapid Synthesis of Fe(PO₃)₃ with Three-dimensional Networks Morphology by a Novel Thermal Decomposition of Iron Phosphonate

Chen Lian^a, Zhang Yinghong^b, Zhou Yiming^a, Xie Kongwei^a, Chen Yu^a, Tang Yawen^a, Lu Tianhong^a

a Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210046;
b Department of Geological Engineering, Nanjing Engineering Vocational College, Nanjing 211135

Received:2011-12-31 Revised:2012-04-25 Published:2012-04-20
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21005039 and 21073094) and the Priority Academic Program Development of Jiangsu Higher Education Institutions.

The high pure Fe(PO₃)₃ with three-dimensional networks structure was synthesized by a novel thermal decomposition of phosphonate. Briefly, the iron phosphonate (Fe^III-edtmpH₅) complex was synthesized by using FeCl₃ and ethylenediamine-tetramethylene phosphonic acid (edtmpH₈) as starting materials. The composition and structure of Fe^III-edtmpH₅ complex is characterized by Fourier transform infrared spectroscopy (FT-IR), electrospray ionization/mass spectrometry (ESI/MS) and thermogravimetry-,differential thermal analysis (TG-DTA). Then, the Fe(PO₃)₃ is obtained by thermal decomposition of Fe^III-edtmpH₅ complex in air atmosphere. X-ray diffractometry (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) measurements show that the obtained Fe(PO₃)₃ possesses high purity, good crystallinity and particular three-dimensional networks morphology.

Key words: iron metaphosphate, phosphonate, complex, thermal decomposition

Cite this article

Chen Lian, Zhang Yinghong, Zhou Yiming, Xie Kongwei, Chen Yu, Tang Yawen, Lu Tianhong. Simple and Rapid Synthesis of Fe(PO₃)₃ with Three-dimensional Networks Morphology by a Novel Thermal Decomposition of Iron Phosphonate[J]. Acta Chimica Sinica, 2012, 70(12): 1412-1416.

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References

1 Haushalter, R. C.; Mundi, L. A. Chem. mater. 1992, 4, 31.

2 Clearfield, A. Chem. Rev. 1988, 88, 125.

3 Rojo, J. M.; Mesa, J. L.; Calvo, R.; Lezama, L.; Olazcuaga, R.; Rojo, T. J. Mater. Chem. 1998, 8,1423.

4 Van der Meer, H. Acta Crystallogr.,Sect. B, 1976, 32, 2423.

5 Middlemiss, N.; Hawthorne, F.; Calvo, C. Can. J. Chem. 1977, 55, 1673.

6 Rojo, J.; Pizarro, J.; Rodriguez-Martinez, L.; Fernandez-Diaz, M.; Fernandez, J. R.; Arriortua, M.; Rojo, T. J. Mater. Chem. 2004, 14, 992.

7 Melnikov, P.; Guirardi, A.; Secco, M. A. C.; Nogueira de Aguiar, E. J. Therm. Anal. Cal. 2008, 94,163.

8 Rojo, J.; Pizarro, J.; Fernandez, J. R.; Greneche, J.; Arriortua, M.; Fernandez-Diaz, M.; Rojo, T. J. Mater. Chem. 2003, 13, 1723.

9 Rojo, J. M.; Mesa, J. L.; Lezama, L.; Rojo, T. J. Solid State Chem. 1999, 145, 629.

10 Zhou, W. J.; He, W.; Zhang, X. D.; Liu, J. N.; Du, Y.; Yan, S. P.; Tian, X. Y.; Sun, X. N.; Han, X. X.; Yue, Y. Z. J. Chem. Eng. Data 2009, 54, 2073.

11 Lesueur, C.; Pfeffer, M.; Fuerhacker, M. Chemosphere 2005, 59, 685.

12 Shen, J.; Jiang, Q.-Y.; Zhong, G.-Q.; Jia, Y.-Q.; Yu, K.-B. Aata Chim. Sinica 2007, 65, 5(in Chinese). （沈娟,蒋琪英,钟国清,贾雨庆,郁开北,化学学报,2007,65,5.）

13 Chen, L.-T.; Liu, T.; Chen, J.-Z. Aata Chim. Sinica 2008, 66, 9(in Chinese). （陈莉涛,刘婷,陈家藏,化学学报,2008,66,9.）

14 Naito, K.; Matsui, M.; Imai, I. Harmful algae 2005, 4, 1021.

15 Princz, E.; Szilagyi, I.; Mogyorosi, K.; Labadi, I. J. Therm. Anal. Cal. 2002, 69, 427.

16 Nowack, B.; Stone, A. T. Environ. Chem. Lett. 2003, 1, 24.

17 Di Marco, V.; Kilyen, M.; Jakusch, T.; Forgo, P.; Dombi, G.; Kiss, T. Eur. J. Inorg. Chem. 2004,2004, 12, 2524.

18 Mateescu, C.; Princz, E.; Bouet, G.; Khan, M. Phosphorus Sulfur 2006, 181, 947.

19 Kim, H.; Lee, J. Y.; Song, K. S.; Seo, Y. H.; Park, S. Y.; Kim, K. H.; Je, H. D.; Han, S. B.; Jeong, J. H. Chromatographia 2010, 71, 595.

20 Briche, S.; Zambon, D.; Boyer, D.; Chadeyron, G.; Mahiou, R. Opt. Mater. 2006, 28, 615.

21 Zhao, J.-Y.; Zhou, Y.-M.; Wu, Y.-S; Tang, Y.-W; Chen, Y.; Lu, T.-H. Acta Chim. Sinica 2011, 69,9(in Chinese). （赵佳越,周益明,吴云盛,唐亚文,陈煜,陆天虹,化学学报,2011,69,9.）

22 Demadis, K. D.; Barouda, E.; Stavgianoudaki, N.; Zhao, H. Cryst. Growth Des. 2009, 9, 1250.23. Labadi, I.; Mogyorosi, K.; Princz, E. J. Eng. Ann. Fac. Eng. Hn.2009, 7. 1584.

24 Liang, Y.; Zhou, Y. M.; Ma, J.; Zhao, J. Y.; Chen, Y.; Tang, Y. W.; Lu, T. H. Appl. Cata. B-Environ. 2011. 103, 388.

25 Pawlak, Z.; Frost, R.; Hargreaves, D. Manuf. Eng. 2009, 37,. 458..

26 Zhang, L. Y.; Ghussn, L.; Schmitt, M. L.; Zanotto, E. D.; Brow, R. K.; Schlesinger, M. E. J. Non-Cryst. Solids 2010, 3, 44.

27 Jouini, A.; Ferid, M.; Gacon, J. C.; Grosvalet, L.; Thozet, A. Mater. res. bull. 2003, 38, 1613.

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有机膦酸配合物热分解法制备三维网状形貌的偏磷酸铁

Simple and Rapid Synthesis of Fe(PO₃)₃ with Three-dimensional Networks Morphology by a Novel Thermal Decomposition of Iron Phosphonate

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