Effect of n-SiO2 on Electrodeposition of Nickel and Chemical Bonding Interaction between Nanoparticles and Matrix Metal in the Composite Coating

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (20): 2010-2014. Previous Articles Next Articles

纳米二氧化硅对镍电沉积影响及在复合镀层中的化学键合状态

涂伟毅, 徐滨士, 董世运, 蒋斌, 杜令忠, 胡振峰

装甲兵工程学院, 装备再制造技术国防科技重点实验室, 北京, 100072

投稿日期:2003-08-31 修回日期:2004-06-10 发布日期:2014-02-17
通讯作者: 涂伟毅,E-mail:weiyitu@sohu.com;Tel:010-66718541 E-mail:weiyitu@sohu.com
基金资助:
国家973项目子项目(No.G1999065009)、国家自然科学基金重点项目(No.50235030)及中英政府科技合作基金(No.2002M3)资助项目.

Effect of n-SiO₂ on Electrodeposition of Nickel and Chemical Bonding Interaction between Nanoparticles and Matrix Metal in the Composite Coating

TU Wei-Yi, XU Bin-Shi, DONG Shi-Yun, JIANG Bin, DU Ling-Zhong, HU Zhen-Feng

State Key Laboratory of Remanufacture Technology, Armored Force Engineering Institute, Beijing 100072

Received:2003-08-31 Revised:2004-06-10 Published:2014-02-17

Abstract

The electrochemical response from n-SiO₂/Ni composite brush plating system was researched by means of cyclicvoltammetry and potential step. The interaction between nanoparticles and matrix metal nickel was investigated by X-ray photoelectron spectrometry. The results show that nanoparticles lead to increasing of the current efficiency, ratio of nucleation and crystal growth rate as well as decreasing of overpotential. Nanoparticles can catalyze the nickel electrodeposition and reduce the size of metal crystal. As the nickel atoms reduced on cathode are diffusing on the metal growth surface, the unsaturated bond of oxygen atoms on nanoparticle surface can capture some of the absorbed nickel atoms and form nickel-oxygen chemical bond. It is proved that the chemical bonding interaction exists on the interface between nanoparticle surface and matrix metal nickel.

Key words: nanoparticle, composite electrodeposition, chemical bonding, co-deposition mechanism

Cite this article

TU Wei-Yi, XU Bin-Shi, DONG Shi-Yun, JIANG Bin, DU Ling-Zhong, HU Zhen-Feng. Effect of n-SiO₂ on Electrodeposition of Nickel and Chemical Bonding Interaction between Nanoparticles and Matrix Metal in the Composite Coating[J]. Acta Chimica Sinica, 2004, 62(20): 2010-2014.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

[1] Derek, V. Metal Finishing 2002, 100(7), 18.
[2] Jack, W. D. Metal Finishing 1997, 95(6), 88.
[3] Subramanian, B.; Sanjeeviraja, C.; Jayachandran, M. J.Cryst. Growth 2002, 234,421.
[4] Hu, S. B.; Tu, J. P.; Mei, Z. Surf. Coat. Technol. 2001,141, 174.
[5] Clarke, R. D. Int. J. Adhes. Adhes. 1999, 19, 205.
[6] Yang, R. P.; Cai, X.; Chen, Q. L. Surf. Coat. Technol.2001, 141, 283.
[7] Ma, Y.-J.; Zhu, Z.-X. Surf. Technol. 2001, 30(6), 5 (in Chinese).(马亚军,朱张校,表面技术,2001,30(6),5.)
[8] Tu, W.-Y.; Xu, B.-S.; Jiang, B. Chin. J. Mater. Res.2003, 17, 530 (in Chinese).(涂伟毅,徐滨士,蒋斌,材料研究学报,2003,17,530.)
[9] Wang, W.; Gau, H.-T.; Gao, J.-P.; Qin, Q.-X. Chin. JMater. Res. 1997, 11(2), 143 (in Chinese).(王为,郭鹤桐,高建平等,覃奇贤,材料研究学报,1997,11(2),143.)
[10] Abyaneh, M. Y.; Fleischmann, M. J. Electroanal. Chem.1981, 119, 187.
[11] Amblard, J.; Forment, M.; Maurin, G.; Spyrellis, N.;Trevisan-Southyrand, E. Elecrtochim. Acta 1983, 28 (7), 909.
[12] Abyaneh, M. Y.; Fleisehmann, M. J. Electroanal. Chem.1981, 119, 197.
[13] Scharifker, B.; Hills, G. Electrochim. Acta 1983, 28(7), 879.
[14] Fleischmann, M.; Tnirsk, H. R. Advances in Electrochemistry and Electrochemical Engineering, Vol. 3, Interscience, New York,1963, Chapter 3.
[15] Galtayries, A.; Grimblot, J. J. Electron Spectrosc. Relat.Phenom. 1999, 98-99, 267.
[16] Wanger, C. D.; Riggs, W. M.; Davis, L. E. Handbook of Xray Photoelectron Spectroscopy, Perkin-Elmer Corporation Physical Electronic Division, Minnesota, 1979.
[17] Zhang, Z.-K.; Cui, Z.-L. Nanometer Technology and Nanometer Materials, National Defence Industry Press, Beijing, 2000, p. 34(in Chinese).(张志昆,崔作林,纳米技术与纳米材料,国防工业出版社,北京,2000,p.34.)
[18] Yin, M.-Z.; Yao, X.; Wu, X.-Q. Chin. J. Mater. Res.2003, 17(2), 220 (in Chinese).(殷明志, 姚熹, 吴小清, 材料研究学报,2003, 17(2),220.)

纳米二氧化硅对镍电沉积影响及在复合镀层中的化学键合状态

Effect of n-SiO₂ on Electrodeposition of Nickel and Chemical Bonding Interaction between Nanoparticles and Matrix Metal in the Composite Coating

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Wenjie Wei, Wenlong Chen, Xiaobin Dai, Li-Tang Yan. Theory of Anomalous Diffusion Dynamics in Biomacromolecular Media^★ [J]. Acta Chimica Sinica, 2023, 81(8): 967-978.
[2]	Fengbin Zheng, Kun Wang, Tian Lin, Yinglong Wang, Guodong Li, Zhiyong Tang. Research Progress on the Preparation of Metal-Organic Frameworks Encapsulated Metal Nanoparticle Composites and Their Catalytic Applications^★ [J]. Acta Chimica Sinica, 2023, 81(6): 669-680.
[3]	Xufa He, Kangle Jia, Longfei Yu, Mingjie Liu, Xiaoshan Zheng, Huanling Li, Jinlan Xin, Linjia Huang. pH-Responsive Pickering Emulsions Synergistically Stabilized by Maleopimaric Acid and Alumina Nanoparticles [J]. Acta Chimica Sinica, 2022, 80(6): 765-771.
[4]	Xuezhi Yang, Dawei Lu, Weichao Wang, Hang Yang, Qian Liu, Guibin Jiang. Nano-Tracing: Recent Progress in Sourcing Tracing Technology of Nanoparticles^※ [J]. Acta Chimica Sinica, 2022, 80(5): 652-658.
[5]	Jinyuan Zhao, Qian Zhang, Jian Wang, Qi Zhang, Heng Li, Yaping Du. Advances in the Scavenging Materials for Reactive Oxygen Species [J]. Acta Chimica Sinica, 2022, 80(4): 570-580.
[6]	Ruomei Liu, Yanhui Feng, Zhuo Li, Shan Lu, Tianyong Guan, Xingjun Li, Yan Liu, Zhuo Chen, Xueyuan Chen. A Novel Near-infrared Responsive Lanthanide Upconversion Nanoplatform for Drug Delivery Based on Photocleavage of Cypate^※ [J]. Acta Chimica Sinica, 2022, 80(4): 423-427.
[7]	Junmin Chen, Chengqian Cui, Hanlin Liu, Guodong Li. Study on the Selective Hydrogenation of Quinoline Catalyzed by Composites of Metal-Organic Framework and Pt Nanoparticles^※ [J]. Acta Chimica Sinica, 2022, 80(4): 467-475.
[8]	Yanran Li, Zigui Wang, Zhaohui Tang. Water Soluble IR-780 Polymer for Mitochondria-Targeted Photodynamic Therapy^※ [J]. Acta Chimica Sinica, 2022, 80(3): 291-296.
[9]	Jinghuang Chen, Tian Meng, Lie Wu, Hengchong Shi, Fan Yang, Jian Sun, Xiurong Yang. Study on Synthesis and Antibacterial Properties of AgNPs@ZIF-67 Composite Nanoparticles^※ [J]. Acta Chimica Sinica, 2022, 80(2): 110-115.
[10]	Ju Huang, Zhen Li, Zhihong Liu. Functionalized Upconversion Nanoparticles for Disassembly of β‑Amyloid Aggregation with Near-Infrared Excitation [J]. Acta Chimica Sinica, 2021, 79(8): 1049-1057.
[11]	Chunhui Mu, Yixin Zhang, Wei Kou, Lianbin Xu. Nickel-Nitrogen-Doped Ordered Macro-/Mesoporous Carbon Supported Ag Nanoparticles for Efficient Electrocatalytic CO₂ Reduction [J]. Acta Chimica Sinica, 2021, 79(7): 925-931.
[12]	Heqi Gao, Di Jiao, Hanlin Ou, Jingtian Zhang, Dan Ding. High Performance Aggregation-Induced Emission Nanoprobes for Image-Guided Cancer Surgery [J]. Acta Chimica Sinica, 2021, 79(3): 319-325.
[13]	Xiaomeng Zhang, Xiya Li, Wanfeng Xiong, Hongfang Li, Rong Cao. Ultrafine Platinum Nanoparticles Derived from Supramolecular Crystal for Catalytic Hydrogenation of Nitroarenes [J]. Acta Chimica Sinica, 2021, 79(2): 180-185.
[14]	Yijun Guo, Bing Wei, Xiang Zhou, Dongbao Yao, Haojun Liang. DNA Walker-Programmed Nanoparticle Superlattice [J]. Acta Chimica Sinica, 2021, 79(2): 192-199.
[15]	Wang Peipei, Liang Tao, Zuo Miaomiao, Li Zhen, Liu Zhihong. A Ratiometric Upconversion Nanoprobe for Detection of HNO Based on Luminescence Resonance Energy Transfer [J]. Acta Chimica Sinica, 2020, 78(8): 797-804.