Acta Chimica Sinica ›› 2021, Vol. 79 ›› Issue (11): 1320-1330.DOI: 10.6023/A21080377 Previous Articles Next Articles
Review
投稿日期:
2021-08-12
发布日期:
2021-09-24
通讯作者:
王晓艳
作者简介:
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李勇, 中国科学院上海有机化学研究所2018级硕士研究生. 2018年本科毕业于中南大学. 目前研究方向为新型烯烃配位聚合催化剂的设计合成. |
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王晓艳, 中国科学院上海有机化学研究所副研究员. 2010年本科毕业于东北林业大学. 2015年在中国科学院长春应用化学研究所取得博士学位. 随后在中国科学院上海有机化学研究所金属有机化学实验室/南开大学化学系进行博士后的研究工作. 2017年正式加入上海有机化学研究所金属有机化学国家重点实验室, 开展新型过渡金属催化剂、“活性”自由基聚合及可控烯烃配位聚合等方面的研究. |
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唐勇, 中国科学院上海有机化学研究所研究员. 1986年本科毕业于四川师范学院; 1992年和1996年先后在中国科学院上海有机化学研究所获得硕士和博士学位. 1996年至1999年先后在美国科罗拉多州立大学和美国乔治城大学从事博士后研究; 1999年5月入职上海有机化学研究所, 2000年1月, 担任上海有机化学研究所“百人计划”项目研究员, 2015年当选中国科学院院士. 主要从事金属有机化学研究, 包括: 不对称催化, 烯烃聚合催化剂的设计、合成与应用, 叶立德化学以及天然产物全合成等. |
基金资助:
Yong Li, Xiao-Yan Wang(), Yong Tang
Received:
2021-08-12
Published:
2021-09-24
Contact:
Xiao-Yan Wang
Supported by:
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Yong Li, Xiao-Yan Wang, Yong Tang. Coordination Polymerization of α,ω-Diolefin: the Regulation of Polymer Microstructure by Catalyst[J]. Acta Chimica Sinica, 2021, 79(11): 1320-1330.
Run | Cat. (μmol) | OD/ hexane/mL | Yield/ mg | Act.b | Mn/ ×104 | Mw/Mn |
---|---|---|---|---|---|---|
1 | 1 (0.3) | 15.0/— | 160 | 1.6 | 76.3 | 1.86 |
2 | 1 (0.3) | 15.0/— | 160 | 1.6 | 66.4 | 1.89 |
3 | 1 (0.1) | 15.0/— | 120 | 3.6 | 81.1 | 1.63 |
4 | 1 (0.1) | 10.0/5.0 | 104 | 3.1 | 61.2 | 1.66 |
5 | 1 (1.0) | 7.5/7.5 | 227 | 6.8 | 37.8 | 2.00 |
6 | 1 (0.1) | 7.5/7.5 | 66.4 | 2.0 | 46.5 | 1.69 |
7 | 1 (1.0) | 5.0/10.0 | 79 | 2.4 | 17.4 | 1.89 |
8 | 2 (0.1) | 15.0/— | 39.0 | 1.2 | 65.1 | 1.70 |
9 | 2 (0.1) | 15.0/— | 39.0 | 1.2 | 65.6 | 1.76 |
Run | Cat. (μmol) | OD/ hexane/mL | Yield/ mg | Act.b | Mn/ ×104 | Mw/Mn |
---|---|---|---|---|---|---|
1 | 1 (0.3) | 15.0/— | 160 | 1.6 | 76.3 | 1.86 |
2 | 1 (0.3) | 15.0/— | 160 | 1.6 | 66.4 | 1.89 |
3 | 1 (0.1) | 15.0/— | 120 | 3.6 | 81.1 | 1.63 |
4 | 1 (0.1) | 10.0/5.0 | 104 | 3.1 | 61.2 | 1.66 |
5 | 1 (1.0) | 7.5/7.5 | 227 | 6.8 | 37.8 | 2.00 |
6 | 1 (0.1) | 7.5/7.5 | 66.4 | 2.0 | 46.5 | 1.69 |
7 | 1 (1.0) | 5.0/10.0 | 79 | 2.4 | 17.4 | 1.89 |
8 | 2 (0.1) | 15.0/— | 39.0 | 1.2 | 65.1 | 1.70 |
9 | 2 (0.1) | 15.0/— | 39.0 | 1.2 | 65.6 | 1.76 |
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