Acta Chimica Sinica ›› 2023, Vol. 81 ›› Issue (10): 1280-1294.DOI: 10.6023/A23050258 Previous Articles Next Articles
Original article
投稿日期:
2023-05-30
发布日期:
2023-08-29
基金资助:
Bo Li, Haiyan Zhou, Haiyan Ma(), Jiling Huang(
)
Received:
2023-05-30
Published:
2023-08-29
Contact:
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Bo Li, Haiyan Zhou, Haiyan Ma, Jiling Huang. Synthesis of Ethylene-Bridged Bis(indenyl) Zirconium, Hafnium Complexes and Their Catalytic Behavior on Selective Propylene Oligomerization: the Effect of 3-Substituent on Indenyl Ring[J]. Acta Chimica Sinica, 2023, 81(10): 1280-1294.
Complex | α/(°) | β/(°) | Zr—Cent/nm |
---|---|---|---|
rac-1 | 125.76 | 61.10 | 0.2227, 0.2231 |
meso-1 | 125.81 | 59.96 | 0.2215, 0.2223 |
meso-2 | 124.82 | 65.37 | 0.2227, 0.2235 |
meso-4 | 124.21 | 64.60 | 0.2231, 0.2238 |
meso-5 | 125.75 | 61.37 | 0.2218, 0.2211 |
meso-6 | 127.68 | 58.08 | 0.2235, 0.2235 |
Complex | α/(°) | β/(°) | Zr—Cent/nm |
---|---|---|---|
rac-1 | 125.76 | 61.10 | 0.2227, 0.2231 |
meso-1 | 125.81 | 59.96 | 0.2215, 0.2223 |
meso-2 | 124.82 | 65.37 | 0.2227, 0.2235 |
meso-4 | 124.21 | 64.60 | 0.2231, 0.2238 |
meso-5 | 125.75 | 61.37 | 0.2218, 0.2211 |
meso-6 | 127.68 | 58.08 | 0.2235, 0.2235 |
Run | Cat. | Tp/℃ | Yield/g | Act./(106 g•mol-Zr-1•h-1) | Mnb/(g•mol-1) | Ally contentc/% |
---|---|---|---|---|---|---|
1 | meso-1 | 40 | 2.046 | 3.27 | 854 | 18.4 |
2 | 60 | 3.165 | 5.06 | 543 | 16.1 | |
3 | 80 | 4.732 | 7.57 | 327 | 15.7 | |
4 | 100 | 2.803 | 4.48 | 254 | 13.3 | |
5 | meso-2 | 40 | 1.932 | 3.09 | 846 | 30.2 |
6 | 60 | 3.016 | 4.83 | 631 | 26.5 | |
7 | 80 | 3.612 | 5.78 | 492 | 23.1 | |
8 | 100 | 2.547 | 4.08 | 316 | 22.8 | |
9 | meso-3 | 40 | 1.124 | 1.80 | 1032 | 41.3 |
10 | 60 | 2.011 | 3.22 | 823 | 36.5 | |
11 | 80 | 2.932 | 4.69 | 535 | 28.1 | |
12 | 100 | 1.773 | 2.84 | 383 | 26.4 | |
13 | rac-1 | 40 | 3.146 | 5.03 | 1764 | 18.7 |
14 | 60 | 3.761 | 6.02 | 1235 | 15.9 | |
15 | 80 | 5.312 | 8.50 | 824 | 14.3 | |
16d | 80 | Trace | — | — | — | |
17e | 80 | Trace | — | — | — | |
18 | 100 | 6.083 | 9.73 | 365 | 13.6 | |
19 | rac-3 | 40 | 2.996 | 4.79 | 2242 | 40.5 |
20 | 60 | 3.542 | 5.67 | 1536 | 35.9 | |
21 | 80 | 4.132 | 6.61 | 941 | 28.3 | |
22 | 100 | 5.547 | 8.88 | 447 | 25.7 |
Run | Cat. | Tp/℃ | Yield/g | Act./(106 g•mol-Zr-1•h-1) | Mnb/(g•mol-1) | Ally contentc/% |
---|---|---|---|---|---|---|
1 | meso-1 | 40 | 2.046 | 3.27 | 854 | 18.4 |
2 | 60 | 3.165 | 5.06 | 543 | 16.1 | |
3 | 80 | 4.732 | 7.57 | 327 | 15.7 | |
4 | 100 | 2.803 | 4.48 | 254 | 13.3 | |
5 | meso-2 | 40 | 1.932 | 3.09 | 846 | 30.2 |
6 | 60 | 3.016 | 4.83 | 631 | 26.5 | |
7 | 80 | 3.612 | 5.78 | 492 | 23.1 | |
8 | 100 | 2.547 | 4.08 | 316 | 22.8 | |
9 | meso-3 | 40 | 1.124 | 1.80 | 1032 | 41.3 |
10 | 60 | 2.011 | 3.22 | 823 | 36.5 | |
11 | 80 | 2.932 | 4.69 | 535 | 28.1 | |
12 | 100 | 1.773 | 2.84 | 383 | 26.4 | |
13 | rac-1 | 40 | 3.146 | 5.03 | 1764 | 18.7 |
14 | 60 | 3.761 | 6.02 | 1235 | 15.9 | |
15 | 80 | 5.312 | 8.50 | 824 | 14.3 | |
16d | 80 | Trace | — | — | — | |
17e | 80 | Trace | — | — | — | |
18 | 100 | 6.083 | 9.73 | 365 | 13.6 | |
19 | rac-3 | 40 | 2.996 | 4.79 | 2242 | 40.5 |
20 | 60 | 3.542 | 5.67 | 1536 | 35.9 | |
21 | 80 | 4.132 | 6.61 | 941 | 28.3 | |
22 | 100 | 5.547 | 8.88 | 447 | 25.7 |
Run | Cat. | Tp/℃ | Dimerb/% | Dimer/mg | β-Mec/% | Act./(105 g•mol-M-1•h-1) | |||
---|---|---|---|---|---|---|---|---|---|
1-P | 4-M-1-P | 2-M-1-P | 2,4-M-1-P | ||||||
1 | meso-4 | 40 | 28.4 | 20.7 | 32.5 | 18.2 | 238 | 49.3 | 4.76 |
2 | 60 | 30.2 | 16.9 | 33.8 | 19.1 | 463 | 47.1 | 9.26 | |
3 | 80 | 29.6 | 14.7 | 36.1 | 19.6 | 510 | 44.3 | 10.2 | |
4 | 100 | 27.9 | 17.7 | 34.5 | 19.9 | 216 | 45.6 | 4.32 | |
5 | meso-5 | 40 | 33.4 | 19.2 | 35.7 | 11.6 | 224 | 52.6 | 4.48 |
6 | 60 | 31.7 | 16.3 | 37.6 | 14.4 | 436 | 48.0 | 8.72 | |
7 | 80 | 33.5 | 16.1 | 36.1 | 14.3 | 454 | 49.6 | 9.08 | |
8 | 100 | 27.6 | 20.4 | 35.2 | 16.8 | 196 | 48.0 | 3.92 | |
9 | meso-6 | 40 | 28.3 | 18.5 | 33.2 | 20.0 | 127 | 46.8 | 2.54 |
10 | 60 | 27.9 | 18.7 | 34.2 | 19.2 | 321 | 46.6 | 6.42 | |
11 | 80 | 29.5 | 16.0 | 39.7 | 14.8 | 438 | 45.5 | 8.76 | |
12 | 100 | 28.6 | 17.3 | 35.4 | 19.7 | 196 | 45.9 | 3.92 | |
13 | rac-4 | 40 | 29.7 | 19.2 | 32.9 | 18.2 | 259 | 48.9 | 5.18 |
14 | 60 | 34.2 | 15.4 | 33.5 | 16.9 | 487 | 49.6 | 9.73 | |
15 | 80 | 29.7 | 16.3 | 39.9 | 14.1 | 620 | 46.0 | 12.4 | |
16 | 100 | 29.4 | 18.6 | 34.2 | 17.7 | 231 | 48.0 | 4.62 | |
17 | rac-5 | 40 | 34.3 | 19.2 | 33.9 | 12.6 | 239 | 53.5 | 4.78 |
18 | 60 | 30.5 | 17.0 | 37.5 | 15.0 | 459 | 47.5 | 9.18 | |
19 | 80 | 33.7 | 16.3 | 35.9 | 14.1 | 498 | 50.0 | 10.0 | |
20 | 100 | 29.0 | 20.0 | 32.9 | 18.1 | 210 | 49.0 | 4.20 | |
21 | meso-7 | 40 | 33.8 | 24.5 | 22.6 | 19.1 | 28 | 58.3 | 0.56 |
22 | 60 | 32.7 | 25.3 | 24.2 | 17.8 | 51 | 58.0 | 1.02 | |
23 | 80 | 33.3 | 26.8 | 21.1 | 18.3 | 71 | 60.1 | 1.42 | |
24 | 100 | 31.8 | 24.9 | 23.6 | 19.7 | 49 | 56.7 | 0.98 | |
25 | rac-7 | 40 | 32.4 | 26.5 | 23.5 | 17.6 | 21 | 58.9 | 0.42 |
26 | 60 | 31.4 | 27.3 | 26.1 | 15.2 | 48 | 58.7 | 0.96 | |
27 | 80 | 26.0 | 29.9 | 19.5 | 24.7 | 77 | 55.9 | 1.54 | |
28 | 100 | 29.7 | 26.2 | 29.5 | 14.6 | 61 | 55.9 | 1.22 |
Run | Cat. | Tp/℃ | Dimerb/% | Dimer/mg | β-Mec/% | Act./(105 g•mol-M-1•h-1) | |||
---|---|---|---|---|---|---|---|---|---|
1-P | 4-M-1-P | 2-M-1-P | 2,4-M-1-P | ||||||
1 | meso-4 | 40 | 28.4 | 20.7 | 32.5 | 18.2 | 238 | 49.3 | 4.76 |
2 | 60 | 30.2 | 16.9 | 33.8 | 19.1 | 463 | 47.1 | 9.26 | |
3 | 80 | 29.6 | 14.7 | 36.1 | 19.6 | 510 | 44.3 | 10.2 | |
4 | 100 | 27.9 | 17.7 | 34.5 | 19.9 | 216 | 45.6 | 4.32 | |
5 | meso-5 | 40 | 33.4 | 19.2 | 35.7 | 11.6 | 224 | 52.6 | 4.48 |
6 | 60 | 31.7 | 16.3 | 37.6 | 14.4 | 436 | 48.0 | 8.72 | |
7 | 80 | 33.5 | 16.1 | 36.1 | 14.3 | 454 | 49.6 | 9.08 | |
8 | 100 | 27.6 | 20.4 | 35.2 | 16.8 | 196 | 48.0 | 3.92 | |
9 | meso-6 | 40 | 28.3 | 18.5 | 33.2 | 20.0 | 127 | 46.8 | 2.54 |
10 | 60 | 27.9 | 18.7 | 34.2 | 19.2 | 321 | 46.6 | 6.42 | |
11 | 80 | 29.5 | 16.0 | 39.7 | 14.8 | 438 | 45.5 | 8.76 | |
12 | 100 | 28.6 | 17.3 | 35.4 | 19.7 | 196 | 45.9 | 3.92 | |
13 | rac-4 | 40 | 29.7 | 19.2 | 32.9 | 18.2 | 259 | 48.9 | 5.18 |
14 | 60 | 34.2 | 15.4 | 33.5 | 16.9 | 487 | 49.6 | 9.73 | |
15 | 80 | 29.7 | 16.3 | 39.9 | 14.1 | 620 | 46.0 | 12.4 | |
16 | 100 | 29.4 | 18.6 | 34.2 | 17.7 | 231 | 48.0 | 4.62 | |
17 | rac-5 | 40 | 34.3 | 19.2 | 33.9 | 12.6 | 239 | 53.5 | 4.78 |
18 | 60 | 30.5 | 17.0 | 37.5 | 15.0 | 459 | 47.5 | 9.18 | |
19 | 80 | 33.7 | 16.3 | 35.9 | 14.1 | 498 | 50.0 | 10.0 | |
20 | 100 | 29.0 | 20.0 | 32.9 | 18.1 | 210 | 49.0 | 4.20 | |
21 | meso-7 | 40 | 33.8 | 24.5 | 22.6 | 19.1 | 28 | 58.3 | 0.56 |
22 | 60 | 32.7 | 25.3 | 24.2 | 17.8 | 51 | 58.0 | 1.02 | |
23 | 80 | 33.3 | 26.8 | 21.1 | 18.3 | 71 | 60.1 | 1.42 | |
24 | 100 | 31.8 | 24.9 | 23.6 | 19.7 | 49 | 56.7 | 0.98 | |
25 | rac-7 | 40 | 32.4 | 26.5 | 23.5 | 17.6 | 21 | 58.9 | 0.42 |
26 | 60 | 31.4 | 27.3 | 26.1 | 15.2 | 48 | 58.7 | 0.96 | |
27 | 80 | 26.0 | 29.9 | 19.5 | 24.7 | 77 | 55.9 | 1.54 | |
28 | 100 | 29.7 | 26.2 | 29.5 | 14.6 | 61 | 55.9 | 1.22 |
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