Electronic Structure Engineering of g-C3N4 via S/B/K Co-Doping for Efficient Photocatalytic H2O2 Synthesis

doi:10.6023/A26040135

Abstract

Efficient photocatalytic reduction of O₂ to H₂O₂ over graphitic carbon nitride (g-C₃N₄) is of significant practical value. To overcome the intrinsic drawbacks of g-C₃N₄ including high electronic structure symmetry, severe photogenerated carrier recombination, weak O₂ activation ability, and low photocatalytic H₂O₂ synthesis efficiency, herein a regulation strategy of electronic structure via multi-element co-doping coupled with defect engineering was proposed. A S/B/K ternary co-doped g-C₃N₄ catalyst (denoted as KBSCN) was fabricated by a facile two-step calcination followed by ionothermal treatment. This strategy enabled the simultaneous homogeneous incorporation of electron-rich S and electron-deficient B into the g-C₃N₄ framework, intercalation of K, as well as the introduction of cyano groups (−C≡N) and nitrogen vacancies (N_v). The structural and photoelectrochemical properties of KBSCN were systematically characterized, and its photocatalytic performance in photocatalytic reduction of O₂ to H₂O₂ was evaluated. Combined with density functional theory (DFT) calculations, the synergistic regulation mechanism of multi-element doping on the electronic structure and reaction kinetics of KBSCN was elucidated. S/B/K ternary co-doping can effectively break the inherent symmetric structure and broaden the visible light response range of g-C₃N₄. In photocatalytic reduction of O₂, under visible light irradiation, KBSCN exhibited a H₂O₂ production rate of 8132 μmol•g⁻¹•h⁻¹, which was 185 times that of pristine g-C₃N₄. Mechanistic studies indicate that S/B/K co-doping greatly promotes the separation and migration of photogenerated carriers by inducing the spatial separation of the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO). Moreover, by combining radical scavenging experiments, in situ electron paramagnetic resonance (EPR), in situ diffuse reflectance infrared Fourier transform (in situ DRIFT) spectroscopy characterizations and Bader charge analysis for electron transfer, it is revealed that S/B/K co-doping drives the photocatalytic O₂ reduction reaction (ORR) to proceed via an indirect two-electron reduction pathway with superoxide radicals (•O₂⁻) as the intermediate, thus significantly boosting the reaction kinetics of the 2e⁻-ORR process. This work provides a new avenue for the design of g-C₃N₄-based catalysts for efficient visible light-driven H₂O₂ synthesis via synergistic regulation of electronic structure and surface reaction kinetics.

Key words: photocatalysis, H₂O₂, g-C₃N₄, multi-element co-doping, synergistic effect

Cite this article

Danning Feng, Bo Feng, Kun Wan, Songhai Xie, Yan Pei, Minghua Qiao, Baoning Zong. Electronic Structure Engineering of g-C₃N₄ via S/B/K Co-Doping for Efficient Photocatalytic H₂O₂ Synthesis[J]. Acta Chimica Sinica, 2026, 84(7): 1140-1152.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

Fig. & Tab. 8

Figure 1. (a) Schematic illustration of the preparation process of KBSCN, SEM images of (b) CN and (c) KBSCN, TEM image of (d) CN, and HRTEM image (e) and (f) EDS mapping images of KBSCN

Figure 2. (a) XRD patterns and (b) FTIR spectra of CN and KxCN

Figure 3. 13C MAS NMR spectra of CN and KBSCN

Figure 4. (a) Survey XPS spectra, (b) C 1s spectra, and (c) N 1s spectra of CN and KxCN. (d) S 2p spectra of KSCN and KBSCN. (e) B 1s spectra of KBCN and KBSCN. (f) K 2p spectra of KxCN

Figure 5. (a) Time-dependent production of H2O2 and (b) comparison of the H2O2 production rate in photocatalytic O2 reduction over CN and KxCN. (c) H2O2 production rate over KBSCN in different atmospheres (O2, air, or N2). (d) Comparison of the H2O2 production rate between KBSCN and reported carbon nitride-based catalysts. (e) AQY obtained at different incident light wavelengths (400, 420, 450, and 500 nm) versus UV-vis DRS of KBSCN. (f) Photocatalytic decomposition of H2O2 (c0=5 mmol•L−1) over CN and KxCN under N2 atmosphere. (g) kf and kd for H2O2 production over CN and KxCN in photocatalytic reduction of O2 to H2O2. (h) Recyclability of KBSCN in photocatalytic O2 reduction to H2O2. All photocatalytic performance data are presented as the average of three independent replicate experiments, and the error bars in the figures represent the standard deviation of three parallel experiments

Figure 6. (a) UV-vis DRS spectra and (b) energy band structure and redox potential for photocatalytic production of H2O2 of CN and KxCN. (c) PL spectra of CN and KxCN. (d) TRPL spectra of CN and KBSCN. (e) Photocurrent response curves and (f) EIS Nyquist plots of CN and KxCN (the inset represents the equivalent circuit for fitting EIS)

Figure 7. (a) H2O2 production rate in the presence of different scavengers over KBSCN (All photocatalytic performance data are presented as the average of three independent replicate experiments, and the error bars in the figure represent the standard deviation of three parallel experiments). (b) EPR signals of DMPO-•O2− generated on CN and KBSCN under dark or visible light irradiation situation. (c) The LSV curves of CN and KBSCN measured at 1600 r•min−1 in O2-saturated 0.1 mol•L−1 KOH solution (pH=13); (d) Selectivity of H2O2 production and electron transfer number derived from LSV test. (e) In situ DRIFT spectra detected on KBSCN upon visible light irradiation at different time intervals (Experimental conditions: visible light irradiation and O2-water vapor atmosphere)

Figure 8. (a) LUMO and HOMO distributions for CN and KxCN. (b) Adsorption energy of O2 on CN and KxCN. (c) Differential charge density of O2 on the active site of CN and KBSCN (The yellow and the cyan regions represent electron accumulation and depletion, respectively). (d) Free energy profiles for photocatalytic ORR over CN and KxCN (The insets show the ORR process occurring on KBSCN). The pink, brown, gray, red, yellow, green, and purple colors represent hydrogen, carbon, nitrogen, oxygen, sulfur, boron, and potassium, respectively

References 57

[1]	Liu, P.; Liang, T.; Li, Y. T.; Zhang, Z. Q.; Li, Z.; Bian, J.; Jing, L. Q. Nat. Commun. 2024, 15, 9224. doi: 10.1038/s41467-024-53482-0
[2]	Cao, D.; Du, J. C.; Li, J. G.; Sun, Q.; Guan, J.; Liu, J. T. ACS Catal. 2025, 15, 3584. doi: 10.1021/acscatal.4c06854
[3]	Wang, D.; Feng, B.; Zhang, X. X.; Liu, Y. N.; Pei, Y.; Qiao, M. H.; Zong, B. N. Acta Chim. Sinica 2022, 80, 772 (in Chinese). doi: 10.6023/A22010030
	(王丹, 封波, 张晓昕, 刘亚楠, 裴燕, 乔明华, 宗保宁, 化学学报, 2022, 80, 772.) doi: 10.6023/A22010030
[4]	Tian, Q.; Jing, L. Y.; Wang, W. Y.; Ye, X. S.; Chai, X. Y.; Zhang, X.; Hu, Q.; Yang, H. P.; He, C. X. Adv. Mater. 2025, 37, 2414490. doi: 10.1002/adma.v37.4
[5]	Wu, Q. Y.; Cao, J. J.; Wang, X.; Liu, Y.; Zhao, Y. J.; Wang, H.; Liu, Y.; Huang, H.; Liao, F.; Shao, M. W.; Kang, Z. H. Nat. Commun. 2021, 12, 483. doi: 10.1038/s41467-020-20823-8
[6]	Xie, Z. S.; Xue, Z. X.; Xu, Z. W.; Li, Q.; Wang, H. Y.; Li, W. S. Acta Chim. Sinica 2022, 80, 1231 (in Chinese). doi: 10.6023/A22040183
	(解众舒, 薛中鑫, 许子文, 李倩, 王洪宇, 李维实, 化学学报, 2022, 80, 1231.) doi: 10.6023/A22040183
[7]	Guo, H. Z.; Zhou, L.; Huang, K.; Li, Y. Q.; Hou, W. D.; Liao, H. G.; Lian, C.; Yang, S. W.; Wu, D. L.; Lei, Z. D.; Liu, Z.; Wang, L. Adv. Funct. Mater. 2024, 34, 2402650. doi: 10.1002/adfm.v34.38
[8]	Li, S. T.; Feng, B.; Zhang, X. X.; Tian, J.; Wang, D.; Pei, Y.; Qiao, M. H.; Li, Y. F.; Zong, B. N. Appl. Catal. B 2023, 335, 122879. doi: 10.1016/j.apcatb.2023.122879
[9]	Zhang, P.; Tong, Y. W.; Liu, Y.; Vequizo, J. J. M.; Sun, H. W.; Yang, C.; Yamakata, A.; Fan, F. T.; Lin, W.; Wang, X. C.; Choi, W. Y. Angew. Chem. Int. Ed. 2020, 59, 16209. doi: 10.1002/anie.202006747 pmid: 32430972
[10]	Zheng, Y. M.; Cui, Y.; Ruan, Q. S.; Zhao, Y. H.; Hou, H.; Zhou, Y.; Ling, C. Y.; Wang, J. L.; Chen, Z. P.; Guo, X. L. ACS Nano 2024, 18, 14583. doi: 10.1021/acsnano.4c02387
[11]	Wu, J. M.; Li, K. Y.; Zhou, B.; Li, R.; Han, Y.; Song, C. S.; Guo, X. W. Adv. Mater. 2025, 38, e19554. doi: 10.1002/adma.v38.8
[12]	Wang, W. K.; Zhang, H. M.; Zhang, S. B.; Liu, Y. Y.; Wang, G. Z.; Sun, C. H.; Zhao, H. J. Angew. Chem. Int. Ed. 2019, 58, 16644. doi: 10.1002/anie.v58.46
[13]	Huang, G. Z.; Li, K. W.; Luo, Y. N.; Zhang, Q.; Pan, Y. L.; Gao, H. L. Acta Chim. Sinica 2024, 82, 314 (in Chinese). doi: 10.6023/A23110484
	(黄广峥, 李坤玮, 罗艳楠, 张强, 潘远龙, 高洪林, 化学学报, 2024, 82, 314.) doi: 10.6023/A23110484
[14]	Zhao, J. H.; Wang, L.; Zhou, T. Y.; Yan, Y. H.; Sun, J. Q.; Hu, B.; Liu, B.; Liu, C. B.; Che, G. B. Small 2025, 21, 2500679. doi: 10.1002/smll.v21.17
[15]	Yan, Y. H.; Zhou, T. Y.; Liu, C. B.; Hu, B.; Che, G. B. Chem. Eng. J. 2025, 516, 164108. doi: 10.1016/j.cej.2025.164108
[16]	Yang, J. D.; Zeng, X. K.; Tebyetekerwa, M.; Wang, Z. Y.; Bie, C. B.; Sun, X.; Marriam, I.; Zhang, X. W. Adv. Energy Mater. 2024, 14, 2400740. doi: 10.1002/aenm.v14.23
[17]	Jiang, Z. X.; Zhang, P.; Che, H. N.; Ao, Y. H. J. Colloid Interface Sci. 2025, 690, 137319. doi: 10.1016/j.jcis.2025.137319
[18]	Xu, Y. S.; He, X.; Zhong, H.; Singh, D. J.; Zhang, L. J.; Wang, R. H. Appl. Catal. B 2019, 246, 349. doi: 10.1016/j.apcatb.2019.01.069
[19]	An, S. F.; Zhang, G. H.; Li, K.; Huang, Z. N.; Wang, X.; Guo, Y. K.; Hou, J. G.; Song, C. S.; Guo, X. W. Adv. Mater. 2021, 33, 2104361. doi: 10.1002/adma.v33.49
[20]	Ren, S. Y.; Yang, X. C.; Liao, L. J.; Hu, W.; Liang, Z. Q.; Wang, S. J.; Zhou, W. Small 2025, 21, 2409352. doi: 10.1002/smll.v21.20
[21]	Zhang, G. G.; Lin, L.; Li, G. S.; Zhang, Y. F.; Savateev, A.; Zafeiratos, S.; Wang, X. C.; Antonietti, M. Angew. Chem. Int. Ed. 2018, 57, 9372. doi: 10.1002/anie.v57.30
[22]	Foo, J. J.; Ng, S. F.; Kok, S. H.; Zeng, X.; Tan, L. L.; Ong, W. J. Chem. Eng. J. 2025, 505, 158992. doi: 10.1016/j.cej.2024.158992
[23]	Sun, J.; Yan, Y.; Yan, L.; Zhou, T.; Wang, L.; Liu, C. Chem. Eng. J. 2025, 524, 169090. doi: 10.1016/j.cej.2025.169090
[24]	Chen, Z.; Savateev, A.; Pronkin, S.; Papaefthimiou, V.; Wolff, C.; Willinger, M. G.; Willinger, E.; Neher, D.; Antonietti, M.; Dontsova, D. Adv. Mater. 2017, 29, 1700555. doi: 10.1002/adma.v29.32
[25]	Shi, Y. X.; Zhu, Q.; Fu, L. L.; Wang, J. X.; Lu, X. Y.; Tao, Y.; Zhang, C.; Wang, Y. J.; Xu, K. N.; Shang, H.; Zhang, D. Q.; Li, G. S. ACS ES&T Water 2025, 5, 242.
[26]	Huang, C. F.; Wen, Y. P.; Ma, J.; Dong, D. D.; Shen, Y. F.; Liu, S. Q.; Ma, H. B.; Zhang, Y. J. Nat. Commun. 2021, 12, 320. doi: 10.1038/s41467-020-20521-5
[27]	Wang, C.; Shi, N.; Zhou, Y.; Lu, Y.; Zhuang, J.; Liao, H.; Ye, C.; Lei, H.; Lin, X.; Zheng, J.; Liu, T. X.; Yuan, Z. Adv. Sci. 2025, 12, e10084. doi: 10.1002/advs.v12.40
[28]	Shang, Y.; Zheng, M.; Liu, H.; Jin, X.; Yan, C.; Song, L.; Qi, Z.; Jing, F.; Song, P.; Zhou, X.; Chen, G.; Lv, C. ACS Catal. 2023, 13, 14530. doi: 10.1021/acscatal.3c03628
[29]	Ma, C.; Zhang, Y.; Yan, S.; Liu, B. Appl. Catal. B 2022, 315, 121574. doi: 10.1016/j.apcatb.2022.121574
[30]	Pedersen, C. J. J. Am. Chem. Soc. 1967, 89, 7017. doi: 10.1021/ja01002a035
[31]	Xiong, T.; Cen, W.; Zhang, Y.; Dong, F. ACS Catal. 2016, 6, 2462. doi: 10.1021/acscatal.5b02922
[32]	Dong, J. T.; Zhao, J. Z.; Yan, X. W.; Li, L.; Liu, G. P.; Ji, M. X.; Wang, B.; She, Y. B.; Li, H. M.; Xia, J. X. Appl. Catal. B 2024, 351, 123993. doi: 10.1016/j.apcatb.2024.123993
[33]	Chen, L.; Ning, S.; Liang, R.; Xia, Y.; Huang, R.; Yan, G.; Wang, X. Int. J. Hydrogen Energy 2022, 47, 14044. doi: 10.1016/j.ijhydene.2022.02.147
[34]	Han, R.; Wang, Y.; Liu, Z.; Wang, J. ACS Appl. Energy Mater. 2025, 8, 883. doi: 10.1021/acsaem.4c02367
[35]	Wang, W.; Zhang, W.; Cai, Y.; Wang, Q.; Deng, J.; Chen, J.; Jiang, Z.; Zhang, Y.; Yu, C. Nano Res. 2023, 16, 2177. doi: 10.1007/s12274-022-4976-0
[36]	Wang, Y. B.; Meng, D.; Zhao, X. Appl. Catal. B 2020, 273, 119064. doi: 10.1016/j.apcatb.2020.119064
[37]	Sun, Y.; Wang, D. Y.; Yang, Y.; Zhao, Q. R.; Yang, S. S.; Luo, X.; Zhao, Q.; Zhang, J. Z. Surf. Interfaces 2024, 51, 104825.
[38]	Zhang, Y. X.; Cao, Q. X.; Meng, A. Y.; Wu, X. L.; Xiao, Y. H.; Su, C. L.; Zhang, Q. T. Adv. Mater. 2023, 35, 2306831. doi: 10.1002/adma.v35.48
[39]	Wang, D.; Elmansour, H.; Li, S.; Zhang, H.; Fu, Y.; Chen, F. Chem. Eng. J. 2025, 515, 163232. doi: 10.1016/j.cej.2025.163232
[40]	Huang, H.; Zhang, Q.; Shi, R.; Su, C.; Wang, Y.; Zhao, J.; Zhang, T. Appl. Catal. B 2022, 317, 121731. doi: 10.1016/j.apcatb.2022.121731
[41]	Xiao, H.; Shan, Y. W.; Wu, S. Y.; Shan, T. S.; Luo, H.; Zhang, F. S.; Huang, L. L.; Chen, L. H.; Liao, G. F. Chem. Eng. J. 2024, 492, 152228. doi: 10.1016/j.cej.2024.152228
[42]	Pan, Y.; Liu, X.; Zhang, W.; Shao, B.; Liu, Z.; Liang, Q.; Wu, T.; He, Q.; Huang, J.; Peng, Z.; Liu, Y.; Zhao, C. Chem. Eng. J. 2022, 427, 132032. doi: 10.1016/j.cej.2021.132032
[43]	Mou, Z. G.; Lu, C.; Yu, K.; Wu, H.; Zhang, H.; Sun, J. H.; Zhu, M. S.; Cynthia Goh, M. Energy Technol. 2019, 7, 1800589. doi: 10.1002/ente.v7.3
[44]	Sun, X.; Yang, J.; Zeng, X.; Guo, L.; Bie, C.; Wang, Z.; Sun, K.; Sahu, A. K.; Tebyetekerwa, M.; Rufford, T. E.; Zhang, X. Angew. Chem. Int. Ed. 2024, 63, e202414417. doi: 10.1002/anie.v63.52
[45]	Duan, L.; Wu, Y.; Zhao, J.; Yu, Z.; Li, S.; Li, J.; Sun, H.; Lu, Y.; Ma, C.; Liu, Q.; Meng, Q. Adv. Funct. Mater. 2025, 35, 2416483. doi: 10.1002/adfm.v35.24
[46]	Shan, T. S.; Wang, Y.; Luo, D.; Huang, Z. C.; Zhang, F. S.; Wu, H.; Huang, L. L.; Li, J. D.; Chen, L. H.; Xiao, H. Appl. Catal. B 2024, 349, 123872. doi: 10.1016/j.apcatb.2024.123872
[47]	Wang, H.; Cao, L. Z.; Tao, X.; Zhu, G. S. Angew. Chem. Int. Ed. 2025, 64, e202502943. doi: 10.1002/anie.v64.21
[48]	Cao, L. Z.; Wang, C.; Wang, H.; Xu, X. M.; Tao, X.; Tan, H. Q.; Zhu, G. S. Angew. Chem. Int. Ed. 2024, 63, e202402095. doi: 10.1002/anie.v63.18
[49]	Zhang, X.; Su, H.; Cui, P.; Cao, Y.; Teng, Z.; Zhang, Q.; Wang, Y.; Feng, Y.; Feng, R.; Hou, J.; Zhou, X.; Ma, P.; Hu, H.; Wang, K.; Wang, C.; Gan, L.; Zhao, Y.; Liu, Q.; Zhang, T.; Zheng, K. Nat. Commun. 2023, 14, 7115. doi: 10.1038/s41467-023-42887-y pmid: 37932292
[50]	Peng, X. Y.; Lei, B.; Tu, Z. X.; He, M.; Luo, Q.; Ding, T. L.; Wu, S. Q.; Peng, G. M. Adv. Funct. Mater. 2025, 36, e22655. doi: 10.1002/adfm.v36.28
[51]	Zhang, X.; Zhou, Q.; Li, C.; Su, H.; Chen, T.; Cui, P.; Ban, C.; Tao, Y.; Wang, J.; Jiang, Y.; Liu, L.; Teng, Z.; Fan, Z.; Zhao, Y.; Zheng, K.; Ding, J.; Su, C.; Zhang, T.; Liu, B. J. Am. Chem. Soc. 2026, 148, 11068. doi: 10.1021/jacs.5c22625
[52]	Zhang, L.; Wang, C.; Jiang, Q.; Lyu, P.; Xu, Y. J. Am. Chem. Soc. 2024, 146, 29943. doi: 10.1021/jacs.4c12339 pmid: 39418115
[53]	Li, C.; Sun, Z.; Song, J.; Tang, B.; Ma, P.; Zhang, R.; Lu, L.; Zheng, K. Angew. Chem. Int. Ed. 2025, 64, e202514661. doi: 10.1002/anie.v64.45
[54]	Yang, S.; Zhang, H.; Wang, J.; Xiang, J.; Fu, Z.; Wang, Y.; Li, Z.; Xie, H.; Tang, S.; Li, Y. Appl. Surf. Sci. 2023, 616, 156523. doi: 10.1016/j.apsusc.2023.156523
[55]	Wang, H.; Yao, Y.; Xiang, Y.; Zhu, X. Sep. Purif. Technol. 2025, 353, 128577. doi: 10.1016/j.seppur.2024.128577
[56]	Chen, Z. W.; Li, J.; Ou, P.; Huang, J. E.; Wen, Z.; Chen, L.; Yao, X.; Cai, G.; Yang, C. C.; Singh, C. V.; Jiang, Q. Nat. Commun. 2024, 15, 359. doi: 10.1038/s41467-023-44261-4 pmid: 38191599
[57]	Li, C.; Song, J.; Ma, P.; Hu, Y.; Sun, Z.; Hu, H.; Zhang, X.; Tang, B.; Zhang, R.; Ma, T.; Zheng, K. Adv. Mater. 2025, 37, 2502918. doi: 10.1002/adma.v37.27

S/B/K共掺杂调控氮化碳电子结构用于高效光催化合成H₂O₂

Electronic Structure Engineering of g-C₃N₄ via S/B/K Co-Doping for Efficient Photocatalytic H₂O₂ Synthesis

RichHTML

PDF

Supporting Info.

Knowledge

Abstract

Cite this article

share this article

Fig. & Tab. 8

References 57

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Huiyan Xu, Aizhu Wang, Longhua Ding, Xin Yu. Advances in Perylene Diimide-Based Photocatalytic Antibacterial Systems and Their Applications [J]. Acta Chimica Sinica, 2026, 84(7): 1197-1210.
[2]	Zijie Zeng, Ziling Peng, Chen Wang, Fatang Tan, Xinyun Wang, Po Keung Wong, Wei Wang. Study on the Nitrogen Vacancy in Carbon Nitride Photocatalysts for Visible-Light-Driven H₂O₂ Production [J]. Acta Chimica Sinica, 2026, 84(6): 879-887.
[3]	Huiying Chen, Ningyu Huang, Peiqin Liao. A Novel Silver-Carbon Bond-Engineered Metal-Organic Framework toward Efficient Artificial Photosynthesis of Hydrogen Peroxide^★ [J]. Acta Chimica Sinica, 2026, 84(5): 626-630.
[4]	Zhongsheng Chen, Tianhao Lei, Wei Peng, Xianlin Chen, Chunpei Yan, Feng Luo. Recent Progress and Prospects of Covalent-organic Frameworks Materials for Uranium Extraction from Seawater^★ [J]. Acta Chimica Sinica, 2026, 84(5): 736-754.
[5]	Chencheng Wang, Banlai Ouyang, Pinyong Zhong, Yingrong Zhang, Jinbiao Liu. Photocatalyzed Desulfurative Cyclization of 2-Aminobenzyl Alcohols and Isothiocyanates for the Synthesis of 2-Amino-1,3-Benzoxazines [J]. Acta Chimica Sinica, 2026, 84(1): 1-7.
[6]	Tongtong Shi, Jia Li, Yifan Yin, Kai Sun. Photochemical Driven Diverse Transformation of α-Trifluoromethyl Olefins [J]. Acta Chimica Sinica, 2026, 84(1): 135-159.
[7]	Qionghui Peng, Jia Peng, Yingli Cai, Zuli Wang, Rongnan Yi, Chao Shen, Weimin He. Ph₂O-Mediated CeO₂-Photocatalyzed Semi-Heterogeneous Fluoroalkylation of 2-Isocyanobiaryls [J]. Acta Chimica Sinica, 2025, 83(9): 1013-1017.
[8]	Zefan Tao, Chunyan Wang, Dawei Yang, Jingping Qu. Synthesis, Characterization and Reactivity of o-Aminobenzenethiolate-Bridged Bimetallic Complexes [J]. Acta Chimica Sinica, 2025, 83(7): 702-708.
[9]	Yuqi Cui, Junyu Li, Jianke Sun. Advances in Porous Organic Cages for Energy Conversion and Storage [J]. Acta Chimica Sinica, 2025, 83(6): 624-638.
[10]	Guokai Li, Binfeng Zhu, Tao Hu, Ruifeng Fan, Weiqing Sun, Zhenxiu He, Jingchao Chen, Baomin Fan. Photoredox Dealkylative Acylation of Tertiary Amines [J]. Acta Chimica Sinica, 2025, 83(3): 199-205.
[11]	Guowei Hu, Xiaohuan Wang, Zhipeng Yuan, Yaer Xinba, Hexige Wuliji. Effect of Ag Doping on the Photocatalytic Performance of Bismuth Ferrite-based Compounds [J]. Acta Chimica Sinica, 2025, 83(3): 229-236.
[12]	Yuping Xiong, Wenlin Xie, Jianqiang Chen, Jie Wu. Photochemical Generation of Sulfide Radical Cations and Their Synthetic Applications [J]. Acta Chimica Sinica, 2025, 83(12): 1592-1618.
[13]	Jian Kang, Zixuan Shi, Jingmei Li. Preparation of Highly Antimicrobial Composites and Study of Photocatalytic Antimicrobial Properties Driven by LED Light [J]. Acta Chimica Sinica, 2024, 82(9): 962-970.
[14]	Kangkui Li, Xianyang Long, Yue Huang, Shifa Zhu. Recent Advances in Visible Light Induced Radical 1,2-Functionalization of Alkynes [J]. Acta Chimica Sinica, 2024, 82(6): 658-676.
[15]	Guangzheng Huang, Kunwei Li, Yannan Luo, Qiang Zhang, Yuanlong Pan, Honglin Gao. Hydrothermal Treatment for Constructing K Doping and Surface Defects in g-C₃N₄ Nanosheets Promote Photocatalytic Hydrogen Production [J]. Acta Chimica Sinica, 2024, 82(3): 314-322.

S/B/K共掺杂调控氮化碳电子结构用于高效光催化合成H2O2