有机化学 ›› 2012, Vol. 32 ›› Issue (01): 57-67.DOI: 10.6023/cjoc1103301 上一篇    下一篇

综述与进展

有机小分子催化的烯酮的不对称环加成反应

王爱娥, 张金龙   

  1. 厦门大学化学化工学院 厦门 361005
  • 收稿日期:2011-03-30 修回日期:2011-05-19 发布日期:2011-06-16
  • 通讯作者: 王爱娥 E-mail:aiewang@xmu.edu.cn
  • 基金资助:

    国家自然科学基金(No. 20902075)、福建省自然科学基金(No. 2009J05037)、高等学校博士学科点专项科研基金(No. 20090121120007)、教育部留学回国人员科研启动基金资助项目.

Organocatalytic Asymmetric Cycloaddition Reaction of Ketenes

Wang Aie, Zhang Jinlong   

  1. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005
  • Received:2011-03-30 Revised:2011-05-19 Published:2011-06-16
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 20902075), the Natural Science Foundation of Fujian Province (No. 2009J05037), the Research Fund for the Doctoral Program of Higher Education of China (No. 20090121120007), and the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry.

重点从立体选择性和催化机理方面, 总结了不同的有机小分子催化剂在烯酮的[2+2]和[4+2]不对称环加成反应中的应用.

关键词: 烯酮, 有机小分子催化, 不对称环加成反应

In this review, organocatalytic asymmetric [2+2] and [4+2] cycloaddition reactions of ketenes are summarized with emphasis on the selectivities and mechanisms of different catalysts.