有机化学 ›› 2012, Vol. ›› Issue (03): 486-496.DOI: 10.6023/cjoc1104225 上一篇    下一篇

综述与进展

异伍兹烷衍生物的研究进展

公绪滨, 孙成辉, 庞思平, 张静, 李玉川, 赵信岐   

  1. 北京理工大学 材料学院 北京 100081
  • 收稿日期:2011-04-22 修回日期:2011-07-19 发布日期:2012-03-24
  • 通讯作者: 孙成辉, 庞思平 E-mail:sunch@bit.edu.cn; pangsp@bit.edu.cn
  • 基金资助:

    教育部新世纪优秀人才支持计划(No. NCET-09-0046)资助项目.

Research Progress in Study of Isowurtzitane Derivatives

Gong Xubin, Sun Chenghui, Pang Siping, Zhang Jing, Li Yuchuan, Zhao Xinqi   

  1. School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081
  • Received:2011-04-22 Revised:2011-07-19 Published:2012-03-24
  • Supported by:

    Project supported by the Program for New Century Excellent Talents in University.

六硝基六氮杂异伍兹烷(HNIW 或CL-20)是当今世界上综合性能最好的单质炸药, 在20 余年的研究过程中, 各国研究者合成出了百余种异伍兹烷衍生物. 根据笼体上取代基的不同以及合成反应的类型, 系统总结了各类衍生物的合成、用途及反应性. 最后对异伍兹烷衍生物的发展方向进行了展望.

关键词: 异伍兹烷衍生物, 高能量密度化合物, 综述

Hexanitrohexaazaisowurtzitane (HNIW or CL-20) is presently the most powerful energetic compound in the world. The synthesis of CL-20 or cage molecules has attracted considerable interest of experts in the area of high-energy materials over the last two decades, and more than 100 isowurtzitane derivatives were synthesized. In this paper, the synthesis, application and reactivity of these compounds are summarized systematically according to different substituents on the cage and types of reactions. The developing tends of isowurtzitane derivatives are also presented.

Key words: isowurtzitane derivatives, high energy density compound, review