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有机化学
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有机化学 ›› 2013, Vol. 33 ›› Issue (01): 178-183.DOI: 10.6023/cjoc201207045 上一篇    下一篇

研究简报

德国小蠊性信息素类似物的设计与合成

王晓波a, 张钟宁b, 杨新玲a   

  1. a 中国农业大学理学院应用化学系 北京 100193;
    b 中国科学院动物研究所农业虫害鼠害综合治理研究国家重点实验室 北京 100101
  • 收稿日期:2012-07-28 修回日期:2012-09-18 发布日期:2012-09-21
  • 通讯作者: 杨新玲 E-mail:yangxl@cau.edu.cn

Design and Synthesis of German Cockroach (Blattella germanica) Sex Pheromone Analogues

Wang Xiaoboa, Zhang Zhongningb, Yang Xinlinga   

  1. a Department of Applied Chemistry, College of Science, China Agricultural University, Beijing 100193;
    b State Key Laboratory of Integrated Management of Pest Insects and Rodents, Institute of Zoology, Chinese Academy of Sciences, Beijing 100101
  • Received:2012-07-28 Revised:2012-09-18 Published:2012-09-21

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德国小蠊是世界上最难治理的卫生害虫之一. 昆虫性信息素可作为一种安全有效的引诱剂用于害虫的综合治理. 德国小蠊性信息素(blattellaquinone)因其结构不稳定而妨碍了它的实际应用. 为了发现结构新颖且稳定的性信息素类似物, 对blattellaquinone的结构中苯醌(A)、酯基(B)和脂肪链(C)部分进行了改造, 设计并合成了一系列类似物, 结构均通过1H NMR, IR和HRMS分析确证.

关键词: 德国小蠊, 小蠊醌, 性信息素类似物, 合成

As one of the most important sanitation pests worldwide, German cockroach (Blattella germanica L.) is difficult to control. Insect sex pheromones are safe and efficient attractants used in integrated pest management. The sex pheromone of German cockroach had been identified as blattellaquinone. The instability hampered the application of this compound. In order to find new and stable structures, a number of analogues were designed and synthesized by modification of the quinone ring (A), aliphatic terminal (B) and ester group (C) of blattellaquinone. The structures were confirmed by 1H NMR, IR spectra and HRMS analysis.

Key words: Blattella germanica, blattellaquinone, sex pheromone analogues, synthesis