有机化学 ›› 2016, Vol. 36 ›› Issue (9): 2075-2090.DOI: 10.6023/cjoc201604005 上一篇    下一篇

综述与进展

镧系金属催化不对称环加成反应研究进展

陈文坤, 杨定乔   

  1. 华南师范大学化学与环境学院 教育部环境理论化学重点实验室 广州 510006
  • 收稿日期:2016-04-03 修回日期:2016-04-29 发布日期:2016-05-19
  • 通讯作者: 杨定乔 E-mail:yangdq@scnu.edu.cn
  • 基金资助:

    国家自然科学基金(Nos.21172081,21372090)、广东省自然科学基金重点(No.S2013020013091)和广州市科技计划(No.156300018)资助项目.

Progress in Lanthanide Metals Catalyzed Asymmetric Cycloaddition Reactions

Chen Wenkun, Yang Dingqiao   

  1. Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, School of Chemistry and Environment, South China Normal University, Guangzhou 510006
  • Received:2016-04-03 Revised:2016-04-29 Published:2016-05-19
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos.21172081, 21372090), the Natural Science Foundation of Guangdong Province (No.S2013020013091) and the City of Guangzhou Science and Technology Plan Projects (No.156300018).

综述了近年来镧系金属催化不对称环加成反应的研究进展,主要包括[4+2]、[3+2]、[2+2]和[2+1]不对称环加成反应.并对部分环加成反应可能的机理进行了讨论.

关键词: 镧系金属催化剂, 不对称环加成, 研究进展

The recent progress in lanthanide metals catalyzed asymmetric cycloaddition reactions is reviewed, mainly including[4+2],[3+2],[2+2] and[2+1] asymmetric cycloaddition reactions. Moreover, the possible mechanisms of some parts of reactions are also discussed.

Key words: lanthanide metals catalyst, asymmetric cycloaddition, research progress