有机化学 ›› 2017, Vol. 37 ›› Issue (12): 3236-3241.DOI: 10.6023/cjoc201605019 上一篇    下一篇

研究论文

苯并三氮唑和2H-氮杂丙烯啶取代反应的研究

刘宁, 段希焱, 周惠云   

  1. 河南科技大学化工与制药学院 洛阳 471023
  • 收稿日期:2017-05-11 修回日期:2017-06-22 发布日期:2017-07-07
  • 通讯作者: 段希焱 E-mail:duanxiyan@tju.edu.cn

Study of the Substitution Reaction between 2H-Azirines and 1H-Benzotriazole

Liu Ning, Duan Xiyan, Zhou Huiyun   

  1. School of Chemical Engineering & Pharmaceutics, Henan University of Science and Technology, Luoyang 471023
  • Received:2017-05-11 Revised:2017-06-22 Published:2017-07-07
  • Contact: 10.6023/cjoc201605019 E-mail:duanxiyan@tju.edu.cn

报道了碳酸钠介导下2-酰氧基-2H-氮杂丙烯啶和苯并三氮唑取代反应.该反应能够高效构筑2-苯并三氮唑-2H-氮杂丙烯啶.该反应的优点为:条件温和、非金属参与以及处理简单.

关键词: 非金属, 取代反应, 2H-氮杂丙烯啶, 苯并三氮唑

new strategy for sodium carbonate-mediated substitution reaction between 2H-azirines and 1H-benzotriazole is reported. This protocol provides an effective way for construction 2-(benzotriazol-1-yl)-2H-azirines. The advantages of this reaction are mild conditions, metal-free and easy operation.

Key words: metal-free, substitution reaction, 2H-azirines, 1H-benzotriazole