Cu(Ⅱ)/Ag(I)催化芳香羧酸和邻氨基苯甲酰胺的选择性脱羧胺化反应

doi:10.6023/cjoc201811010

有机化学 ›› 2019, Vol. 39 ›› Issue (4): 1153-1159.DOI: 10.6023/cjoc201811010 上一篇下一篇

研究简报

Cu(Ⅱ)/Ag(I)催化芳香羧酸和邻氨基苯甲酰胺的选择性脱羧胺化反应

沈丽, 张洁, 谢建伟

石河子大学化学化工学院/新疆兵团化工绿色过程重点实验室-省部共建国家重点实验室培育基地石河子 832003

收稿日期:2018-11-05 修回日期:2018-12-15 发布日期:2018-12-28
通讯作者: 谢建伟 E-mail:cesxjw@foxmail.com
基金资助:
国家自然科学基金（No.21606153，21868032）资助项目.

Cu(Ⅱ)/Ag(I)-Catalyzed Selective Decarboxylated Amination of Aromatic Carboxylic Acids with o-Aminobenzamides

Shen Li, Zhang Jie, Xie Jianwei

School of Chemistry and Chemical Engineering/Key Laboratory for Green Processing of Chemical Engineering of Xinjian Bingtuan, Shihezi University, Shihezi 832003

Received:2018-11-05 Revised:2018-12-15 Published:2018-12-28
Contact: 10.6023/cjoc201811010 E-mail:cesxjw@foxmail.com
Supported by:
Project supported by the National Natural Science Foundation of China (Nos.21606153,21868032).

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1. Cu(Ⅱ)/Ag(I)催化芳香羧酸和邻氨基苯甲酰胺的选择性脱羧胺化反应.PDF(1582KB)

摘要/Abstract

以Cu （OTf）₂和AgOTf为催化剂，研究了取代邻硝基苯甲酸和取代邻氨基苯甲酰胺的选择性C-N交叉偶联反应，以中等收率合成了17个二芳基胺类苯甲酰胺.该方法为芳香胺的选择性N-芳基化提供了一种新的选择.

关键词: 脱羧反应, 选择性胺化, 邻硝基苯甲酸, 邻氨基苯甲酰胺

Cu(OTf)₂/AgOTf-catalyzed selective decarboxylation C-N crossing coupling of o-nitro aromatic carboxylic acids with o-aminobenzamides has been establised, affording seventeen diarylaminobenzamides in moderate yields. The present protocol provides a new choice for selective N-arylation of amines.

Key words: decarboxylation, selective amination, o-nitro aromatic carboxylic acid, o-aminobenzamide

引用此文

沈丽, 张洁, 谢建伟. Cu(Ⅱ)/Ag(I)催化芳香羧酸和邻氨基苯甲酰胺的选择性脱羧胺化反应[J]. 有机化学, 2019, 39(4): 1153-1159.

Shen Li, Zhang Jie, Xie Jianwei. Cu(Ⅱ)/Ag(I)-Catalyzed Selective Decarboxylated Amination of Aromatic Carboxylic Acids with o-Aminobenzamides[J]. Chin. J. Org. Chem., 2019, 39(4): 1153-1159.

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Cu(Ⅱ)/Ag(I)催化芳香羧酸和邻氨基苯甲酰胺的选择性脱羧胺化反应

Cu(Ⅱ)/Ag(I)-Catalyzed Selective Decarboxylated Amination of Aromatic Carboxylic Acids with o-Aminobenzamides

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