有机化学 ›› 2019, Vol. 39 ›› Issue (8): 2139-2147.DOI: 10.6023/cjoc201903069 上一篇    下一篇

所属专题: 陈茹玉先生诞辰100周年

综述与进展

含硫香精香料的合成进展

王明a, 王翠红a, 姜雪峰a,b   

  1. a 华东师范大学化学与分子工程学院 上海市绿色化学与化工过程绿色化重点实验室 上海 200062;
    b 南开大学 元素有机化学国家重点实验室 天津 300071
  • 收稿日期:2019-03-29 修回日期:2019-04-22 发布日期:2019-05-10
  • 通讯作者: 王翠红, 姜雪峰 E-mail:xfjiang@chem.ecnu.edu.cn;chwang@chem.ecnu.edu.cn
  • 基金资助:

    国家重点研发计划(2017YFD0200500)、国家自然科学基金(Nos.21722202,21672069,21871089)资助项目.

Recent Progress in the Sulfur-Containing Perfume & Flavors Construction

Wang Minga, Wang Cuihonga, Jiang Xuefenga,b   

  1. a Shanghai Key Laboratory of Green Chemistry and Chemical Process, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062;
    b State Key Laboratory of Elemento-organic Chemistry, Nankai University, Tianjin 300071
  • Received:2019-03-29 Revised:2019-04-22 Published:2019-05-10
  • Contact: 10.6023/cjoc201903069 E-mail:xfjiang@chem.ecnu.edu.cn;chwang@chem.ecnu.edu.cn
  • Supported by:

    Project supported by the National Key Research and Development Program of China (No. 2017YFD0200500), and the National Natural Science Foundation of China (Nos. 21722202, 21672069, 21871089).

随着科技水平的提高,高精度的分析方法及设备被开发,科学家也在食品中发现了越来越多的含硫化合物.2015年,美国食品香料与萃取制造者协会公布的2816种被认为安全的香料中,含硫化合物有388多种,占总数的13%以上.含硫香料的主要表现为食物特别是副食和菜肴相关的香味,其主要被用作食品香精及花香和果香型日用香精.由于需求量的增加,含硫香料的生产规模也在不断的增加,其合成方法的研究也在不断的深入,绿色、高效的构建方法也不断的被报道.对硫醚、硫醇、硫酯及多硫等香精香料分子的最新构建方法进行概述.

关键词: 硫醚, 硫醇, 硫酯, 多硫, 香精, 香料

Scientists have found more and more sulfur compounds in food with the development of science and technology, high-precision analytical methods and equipment. In 2015, Flavor and Extract Manufactures Association of the United State published 2816 safe flavors, and there are more than 388 sulfur-containing compounds, accounting for more than 13%. The main smell of sulfur-containing flavors is food, especially the non-staple food and dishes. It is mainly used as food flavor, flower flavor and fruity flavor. Due to the increase of sulfur-containing perfume and flavors demand, its production scale is increasing, the research on synthesis methods is also deepening, and the green and efficient construction methods are also constantly reported. In this review, the recent progress in the construction of sulfide, thiol, thioester and polysulfide perfume & flavors is summarized.

Key words: sulfide, thiol, thioester, polysulfide, perfume, flavors