β,β-双取代烯酰胺的不对称催化氢硅化反应

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张振锋^*()

Zhenfeng Zhang()

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张振锋. β,β-双取代烯酰胺的不对称催化氢硅化反应[J]. 有机化学, 2023, 43(1): 365-367.

Zhenfeng Zhang. Catalytic Asymmetric Hydrosilylation of β,β-Disubstituted Enamides[J]. Chinese Journal of Organic Chemistry, 2023, 43(1): 365-367.

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图1. 手性α-氨基硅烷活性分子

Figure 1. Chiral α-aminosilane bioactive compounds

图式1. 手性α-氨基硅烷逆合成分析

Scheme 1. Retrosynthetic analysis of chiral α-aminosilanes

图式2. 手性α-氨基硅烷的高效不对称氢硅化合成

Scheme 2. Efficient synthesis of chiral α-aminosilanes via asymmetric hydrosilylation

图式3. 手性α-氨基硅烷立体发散性合成

Scheme 3. Stereodivergent synthesis of chiral α-aminosilanes

图式4. 不对称氢硅化催化循环

Scheme 4. Catalytic cycle of asymmetric hydrosilylation

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