有机化学 ›› 2024, Vol. 44 ›› Issue (6): 1831-1852.DOI: 10.6023/cjoc202401004 上一篇    下一篇

综述与进展

关于惰性含氟温室气体转化与利用的研究进展

邹震雷a,b,†, 李和寅b,†, 黄梦君b, 沈胤朴b, 刘继阳b, 王之兆b, 张为钢b,*(), 王毅b,*(), 潘毅b   

  1. a 铜陵学院电气工程学院 光电子应用安徽省工程技术研究中心仿生能源实验室 安徽铜陵 244000
    b 南京大学化学化工学院 配位化学国家重点实验室 江苏省先进有机材料重点实验室 南京 210033
  • 收稿日期:2024-01-05 修回日期:2024-02-02 发布日期:2024-02-27
  • 作者简介:
    共同第一作者
  • 基金资助:
    国家自然科学基金(21971107); 国家自然科学基金(22071101); 国家自然科学基金(22271147); 铜陵学院基金(2023tlxyrc15)

Recent Advances in Conversion and Use of Inert Fluorinated Greenhouse Gases

Zhenlei Zoua,b,†, Heyin Lib,†, Mengjun Huangb, Yinpu Shenb, Jiyang Liub, Zhizhao Wangb, Weigang Zhangb,*(), Yi Wangb,*(), Yi Panb,*   

  1. a AnHui Technology Research Center of Optoelectronic Technology Appliance, Biomimetic Energy Laboratory, School of Electrical Engineering, Tongling University, Tongling, Anhui 244000
    b State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, Collaborative Innovation Center of Advanced Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210033
  • Received:2024-01-05 Revised:2024-02-02 Published:2024-02-27
  • Contact: * E-mail: zwgqlsfxy@163.com;yiwang@nju.edu.cn
  • About author:
    These authors contributed equally to this work.
  • Supported by:
    National Natural Science Foundation of China(21971107); National Natural Science Foundation of China(22071101); National Natural Science Foundation of China(22271147); Foundation of Tongling University(2023tlxyrc15)

过去的几十年里, 含氟气体因其特殊理化性质, 在人类社会中的应用几乎随处可见, 为人们的生产生活提供了诸多便利的同时, 正悄无声息地引起一系列环境危机. 长期研究表明含氟气体所造成的温室效应远高于其他温室气体, 人们不得不对含氟气体的使用进行重新评估. 为有效实现含氟气体的经济效益最大化及降低环境污染, 科学家们正努力开发含氟温室气体转化利用的新方法. 综述了近20年国内外化学家针对氟利昂、硫酰氟、三氟化氮和六氟化硫等惰性含氟温室气体转化与利用的最新研究成果.

关键词: 惰性含氟温室气体, 氟利昂, 硫酰氟, 三氟化氮, 六氟化硫

Over the past few decades, fluorinated greenhouse gases have been used almost everywhere in human society due to their special physical and chemical properties. In spite of the convenience they provide to peopleʼs production and life, they also cause many environmental problems. The relevant studies have shown that the release of fluorinated gases causes a more serious greenhouse effect than normal greenhouse gases. Therefore, the use of fluorinated gases must be reassessed. In order to maximize the economic benefits of fluorinated gases and reduce their environmental pollution, scientists all over the world are trying to develop new methods for the conversion and utilization of fluorinated greenhouse gases. we aim to provide an overview of the conversion and utilization of fluorinated greenhouse gases, such as freon, sulfuryl fluoride, nitrogen trifluoride and sulfur hexafluoride from 2000 to 2023.

Key words: inert fluorinated greenhouse gas, freon, sulfuryl fluoride, nitrogen trifluoride, sulfur hexafluoride