异相催化固定二氧化碳合成羰基衍生物的研究进展

doi:10.6023/cjoc202405033

摘要/Abstract

异相催化固定CO₂的反应作为一种将CO₂资源化利用的有效途径, 对促进“碳中和”与“碳达峰”具有重要意义, 并且该反应的探究对于其他催化体系的建立也具有指导意义. 重点介绍了使用异相催化技术在光催化、电催化、热催化、光热催化与光电催化中固定CO₂合成系列羰基衍生物反应的最新研究进展, 主要介绍了不同异相催化剂催化CO₂制备系列羰基衍生物的反应, 且采用不同催化方式进行了系统分类, 讨论了这些反应的反应机制, 为今后设计与实现异相催化固定CO₂反应提供了参考.

关键词: 异相催化, 固定二氧化碳, 羰基衍生物

As an effective way to utilize CO₂ resources, multiphase catalytic carbon fixation is of great significance to promote carbon neutrality and carbon peak. The exploration of this reaction is of guiding significance to the establishment of other catalytic systems. This paper reviews the recent progress in the synthesis of a series of carbon dioxide fixed carbonyl derivatives by heterogeneous catalysis in the fields of photocatalysis, electrocatalysis, thermal catalysis, and photothermal catalysis. The synthesis of carbonyl derivatives by different heterogeneous catalysis CO₂, including organic carbonates, carbamates and carboxylic acids, is introduced. The reaction mechanism of these reactions is discussed. This provides a reference for the design and realization of the polyphase catalytic fixed CO₂ reaction.

Key words: heterogeneous catalysis, fixation of carbon dioxide, carbonyl derivatives

引用此文

张誉元, 杨昌杰, 唐海涛, 潘英明. 异相催化固定二氧化碳合成羰基衍生物的研究进展[J]. 有机化学, 2024, 44(10): 3077-3090.

Yuyuan Zhang, Changjie Yang, Haitao Tang, Yingming Pan. Heterogeneous Catalytic Fixation of Carbon Dioxide for Synthesis of Carbonyl Derivatives[J]. Chinese Journal of Organic Chemistry, 2024, 44(10): 3077-3090.

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图/表 18

图1. 异相催化固定二氧化碳合成羰基衍生物

Figure 1. Heterogeneous catalytic synthesis of carbonyl derivatives from carbon dioxide

图2. CuAg NWs固定CO2生成羧酸

Figure 2. CuAg NWs fixes CO2 to produce carboxylic acids

图3. Ag-CeO2 NWs固定CO2生成苯乳酸

Figure 3. Ag-CeO2 NWs fixed CO2 to produce phenyllactic acid

图4. Cu-SnO2还原CO2生成甲酸

Figure 4. Cu-SnO2 reduces CO2 to formic acid

图5. HNSs固定CO2生成环状碳酸酯

Figure 5. HNSs fixed CO2 to produce cyclic carbonates

图6. d-BCN固定CO2生成羧酸

Figure 6. d-BCN fixed CO2 to produce carboxylic acids

图7. OH-P[5]-on-COF固定CO2生成环状碳酸酯

Figure 7. OH-P[5]-on-COF fixed CO2 to produce cyclic carbonates

图8. Mg-NC固定CO2生成环状碳酸酯

Figure 8. Mg-NC fixed CO2 to produce cyclic carbonates

图9. CTO固定CO2生成N-甲基甲酰苯胺

Figure 9. CTO fixed CO2 to produce N-methylformylanilide

图10. Au-MOFs固定CO2生成羧酸

Figure10. Au-MOFs fixed CO2 to produce carboxylic acids

图11. POMP-NHC-Ir固定CO2生成酰胺化合物

Figure 11. POMP-NHC-Ir fixed CO2 to produce amide compound

图12. Ir1-WO3固定CO2生成环状碳酸酯

Figure 12. Ir1-WO3 fixed CO2 to produce cyclic carbonates

图13. {(ME2NH2)2[Co3(BCP)2]•6H2O•4DMF}n固定CO2生成噁唑烷酮

Figure 13. {(ME2NH2)2[Co3(BCP)2]•6H2O•4DMF}n fixed CO2 to produce oxazolidinones

图14. PIL-s1-HCO3固定CO2生成甲酰胺产物

Figure 14. PIL-s1-HCO3 fixed CO2 to produce formamide products

图15. Cu@NHC-1固定CO2生成噁唑烷酮

Figure 15. Cu@NHC-1 fixed CO2 to produce oxazolidinones

图16. Ag@POP-NL-3固定CO2生成环状碳酸酯

Figure 16. Ag@POP-NL-3 fixed CO2 to produce cyclic carbonate ester

图17. 光电催化CdS/VS-MoS2还原CO2

Figure 17. Photocatalytic reduction of CO2 via CdS/VS-MoS2

图18. 光热条件下CoFe2O4@TPA固定CO2生成碳酸酯

Figure 18. CoFe2O4@TPA fixes CO2 to produce carbonate under photothermal conditions

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