硅基配体介导的碳氢官能化反应研究

doi:10.6023/cjoc202406014

有机化学

综述与进展

硅基配体介导的碳氢官能化反应研究

高吉慧, 何川^*

南方科技大学化学系和格拉布斯研究院深圳 518055

收稿日期:2024-06-11 修回日期:2024-07-18
基金资助:
国家自然科学基金(Nos. 22122102 and 22271134)、广东省催化重点实验室(No. 2020B121201002)、广东省珠江青年拔尖人才(No. 2019QN01Y628)、深圳市科技创新委员会(Nos. RCJC20221008092723013 and JCYJ20230807093104009)资助项目.

X-Type Silyl Ligands Mediated C-H Functionalization Reactions

Jihui Gao, Chuan He^*

Shenzhen Grubbs Institute and Department of Chemistry, Southern University of Science and Technology, Shenzhen, 518055

Received:2024-06-11 Revised:2024-07-18
Contact: *E-mail: hec@sustech.edu.cn
Supported by:
National Natural Science Foundation of China (Nos. 22122102 and 22271134), the Guangdong Provincial Key Laboratory of Catalysis (No. 2020B121201002), the Guangdong Pearl River Talent Program (No. 2019QN01Y628), and the Shenzhen Science and Technology Innovation Committee (Nos. RCJC20221008092723013 and JCYJ20230807093104009).

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摘要/Abstract

研究和发展新型配体对于过渡金属(TM)催化具有重要意义. 随着有机硅化学的快速发展,综述X型硅基配体参与的过渡金属催化反应这一话题非常必要且具有吸引力. 本综述旨在探讨硅基配体独特的σ-供电子能力和反位效应,阐述它们在碳氢官能化反应中对反应活性和选择性起到的关键作用. 此外,综述还对该领域未来的发展趋势进行了展望,希望能为催化合成化学领域提供新的思路和启发.

关键词: X型硅基配体, σ-给电子特性, 反位效应, 碳氢官能化, 硼化反应, 硅化反应

The development of novel ligands for transition-metal (TM) catalysis holds significant importance. With the rapid evolution of organosilicon chemistry, summarizing the topic of X-type silyl ligands for TM catalysis is appealing and timely. This review aims to emphasize the unique σ-donating characteristics and trans-effects of silyl ligands, highlighting their pivotal role in enhancing the reactivity and selectivity of C-H functionalization reactions. Furthermore, the review offers valuable insights into future advancements in this field, with the goal of inspiring new applications and perspectives in the realm of catalytic synthetic chemistry.

Key words: X-type silyl ligands, σ-donating characteristics, trans-effects, C-H functionalization, borylation, silylation

引用此文

高吉慧, 何川. 硅基配体介导的碳氢官能化反应研究[J]. 有机化学, doi: 10.6023/cjoc202406014.

Jihui Gao, Chuan He. X-Type Silyl Ligands Mediated C-H Functionalization Reactions[J]. Chinese Journal of Organic Chemistry, doi: 10.6023/cjoc202406014.

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硅基配体介导的碳氢官能化反应研究

X-Type Silyl Ligands Mediated C-H Functionalization Reactions

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