有机化学 ›› 1983, Vol. 3 ›› Issue (6): 440-442. 上一篇    下一篇

研究论文

烯丙醇化合物的不对称环氧化

吴碧琪;张联;周维善   

  1. 中国科学院上海有机化学研究所
  • 发布日期:1983-12-25

Asymmetric epoxidations of allylic alcohols

WU BIQI;ZHANG LIAN;ZHOU WEISHAN   

  • Published:1983-12-25

关键词: 环氧化反应, 对映体, 丙烯醇, 不对称反应

The asymmetric epoxidation of three allylic alcohols (1-3) are described. The enantiomeric excess of the epoxyalcohol (obtained from the trans-allylic alcohol 2) was greater than that from the cis-allylic alcohol. The asymmetric epoxidation of the tertiary allylic alcohol yielded epoxy alcohol, of which the enantiomeric excess was only 4%.

Key words: EPOXIDATION REACTION, ENANTIOMORPH, PROPENOL

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